How substituents at boron atoms affect the CH-acidity and the electron-withdrawing effect of the ortho-carborane cage: A close look on the 1H NMR spectra
IB Sivaev, SA Anufriev, AV Shmalko - Inorganica Chimica Acta, 2023 - Elsevier
Based on the data of 1 H NMR spectra, the effect of various substituents at boron atoms in
different positions of the ortho-carborane cage on its CH-acidity and the electron …
different positions of the ortho-carborane cage on its CH-acidity and the electron …
Accurate single crystal and gas-phase molecular structures of acenaphthene: A starting point in the search for the longest C–C bond
YV Vishnevskiy, AA Otlyotov, JH Lamm… - Physical Chemistry …, 2023 - pubs.rsc.org
The molecular structure of acenaphthene has been determined experimentally in the gas
phase using gas electron diffraction intensities and literature-available rotational constants …
phase using gas electron diffraction intensities and literature-available rotational constants …
Cationic nido-Tricarbollide μ-10,11-H-10,11-H2-7-Me3N-nido-7,8,9-C3B8H8+ and Its Halogenated Derivatives: The Slow Iodination Process Occurring …
J Holub, M Bakardjiev, D Bavol, J Vrána… - Inorganic …, 2025 - ACS Publications
A series of nido-tricarbollides based on 10, 11-X2-7-Me3N-nido-7, 8, 9-C3B8H8 (X= H, Cl,
Br, I) and their protonated, ie cationic, counterparts, which have an extra H-bridge over the …
Br, I) and their protonated, ie cationic, counterparts, which have an extra H-bridge over the …
Synthesis and Crystal Structure of 9,12-Dibromo-ortho-Carborane
OB Zhidkova, AA Druzina, SA Anufriev, KY Suponitsky… - Molbank, 2022 - mdpi.com
Molbank | Free Full-Text | Synthesis and Crystal Structure of 9,12-Dibromo-ortho-Carborane
Next Article in Journal 6-(2′-(4″-Oxabutyloxy)phenyl)-1,6,11-triaza-3,9,14,17,22,25-hexaoxa-2(1,2)(4-methylbenzena)-10(1,2)(5-methylbenzena)bicyclo(9.8.8)heptacosaphane …
Next Article in Journal 6-(2′-(4″-Oxabutyloxy)phenyl)-1,6,11-triaza-3,9,14,17,22,25-hexaoxa-2(1,2)(4-methylbenzena)-10(1,2)(5-methylbenzena)bicyclo(9.8.8)heptacosaphane …
Noncatalytic Bromination of Icosahedral Dicarboranes: The Key Role of Anionic Bromine Clusters Facilitating Br Atom Insertion into the B–H σ-Bond
AV Shernyukov, GE Salnikov, DA Rudakov… - Inorganic …, 2021 - ACS Publications
The mechanism of the noncatalytic bromination of carboranes was studied experimentally
and theoretically. We found that the reactions of o-and m-carboranes 1 and 2 with elemental …
and theoretically. We found that the reactions of o-and m-carboranes 1 and 2 with elemental …
[BOOK][B] Equilibrium Structure of Free Molecules: Theory, Experiment, and Data Analysis
N Vogt, J Demaison - 2023 - books.google.com
The properties of chemical, pharmaceutical, and biological compounds depend mainly on
their molecular structure, whose determination is of fundamental interest. This book …
their molecular structure, whose determination is of fundamental interest. This book …
Database with Equilibrium Structures of Free Molecules
N Vogt, J Demaison - Equilibrium Structure of Free Molecules: Theory …, 2023 - Springer
Equilibrium structures of free molecules determined by experimental methods and published
after 2017 are systematized. The presentation of structural datasets is similar to that in the …
after 2017 are systematized. The presentation of structural datasets is similar to that in the …
Solid-state molecular structures of Se(IV) and Te(IV) dihalides X2Se(CH3)(C6F5) and the gas-phase structure of Se(CH3)(C6F5)
T Glodde, B Neumann, HG Stammler… - … für Naturforschung B, 2023 - degruyter.com
In a systematic study the Se (IV) and Te (IV) dihalides F2E (CH3)(C6F5), Cl2E (CH3)(C6F5)
and Br2E (CH3)(C6F5)(E= Se, Te) have been synthesized and their crystal and molecular …
and Br2E (CH3)(C6F5)(E= Se, Te) have been synthesized and their crystal and molecular …
Equilibrium Structure of Free Molecules
N Vogt, J Demaison - Springer
A considerable amount of work in chemistry has been devoted to the determination and
explanation of molecular structures and its resulting application to the dynamics of …
explanation of molecular structures and its resulting application to the dynamics of …
[HTML][HTML] Institute of Inorganic Chemistry of the Czech Academy of Sciences
AV Strategy, M Londesborough - iic.cas.cz
Among metallacarboranes, particularly the bis (icosahedral) cobalt bis (dicarbollide)(1-) ion
(1-) represents a promising platform for advanced applications, due to sandwich structure …
(1-) represents a promising platform for advanced applications, due to sandwich structure …