Comprehensive Summary Construction of C—F bonds is a direct and efficient method for
introducing fluorine into pharmaceuticals, agrochemicals, and materials. Strategies such as …

In 2015, we reported a photochemical method for directed C–C bond cleavage/radical
fluorination of relatively unstrained cyclic acetals using Selectfluor and catalytic 9 …

The unique and desirable properties of fluorinated compounds in pharmaceutical,
agrochemical, and materials sciences have driven the development of remote fluorination …

β-and γ-fluorinated ketones are desirable moieties in building blocks for bioactive
molecules. Recent progress in installing this functionality has centered around ring-opening …

We describe an asymmetric organocatalytic method to synthesize 1, 7-dicarbonyl
compounds containing a β-stereocenter. The chemistry relies on the formation of γ-keto …

Ring opening of cycloalkanols has been employed as a commonly used strategy to prepare
diverse distal functionalized ketones. However, most of these ketones obtained by this …

A combination of silver nitrate (AgNO3) catalyst and Selectfluor® was found to perform
radical deoxyfluorination of cesium oxalates derived from corresponding alcohols. The …

A manganese‐catalyzed regioselective ring‐opening peroxidation of cyclobutanols has
been disclosed. With this protocol, the C (sp3)− OOBu‐t bond could be efficiently …

Herein we described an access to biaryl lactones from ortho-aryl benzoic acids via
intramolecular O–H/C–H oxidative coupling with the commonly used cerium ammonium …

Radical ring-opening oxyimidation of cyclobutanols and cyclopropanols with the formation of
ω-functionalized ketones was discovered. The oxidative C–O coupling proceeds via the …