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Aqueous iron (IV)–oxo complex: an emerging powerful reactive oxidant formed by iron (II)-based advanced oxidation processes for oxidative water treatment
Z Wang, W Qiu, S Pang, Q Guo, C Guan… - … Science & Technology, 2022 - ACS Publications
High-valent iron (IV)–oxo complexes are of great significance as reactive intermediates
implicated in diverse chemical and biological systems. The aqueous iron (IV)–oxo complex …
implicated in diverse chemical and biological systems. The aqueous iron (IV)–oxo complex …
High-valent nonheme iron-oxo complexes: Synthesis, structure, and spectroscopy
AR McDonald, L Que Jr - Coordination Chemistry Reviews, 2013 - Elsevier
High-valent iron-oxo intermediates have often been implicated, and in some cases
identified, as the active oxidant in oxygen activating nonheme iron enzymes. Recent …
identified, as the active oxidant in oxygen activating nonheme iron enzymes. Recent …
Advancing Fenton and photo-Fenton water treatment through the catalyst design
AV Vorontsov - Journal of Hazardous Materials, 2019 - Elsevier
The review is devoted to modern Fenton, photo-Fenton, as well as Fenton-like and photo-
Fenton-like reactions with participation of iron species in liquid phase and as heterogeneous …
Fenton-like reactions with participation of iron species in liquid phase and as heterogeneous …
C H Bond Activation in Transition Metal Species from a Computational Perspective
Alkanes constitute the cheapest and most abundant feedstock for organic chemicals.
However, the redistribution of CsC and CsH bonds in hydrocarbons into more sophisticated …
However, the redistribution of CsC and CsH bonds in hydrocarbons into more sophisticated …
Catalytic C− H bond amination from high-spin iron imido complexes
ER King, ET Hennessy, TA Betley - Journal of the American …, 2011 - ACS Publications
Dipyrromethene ligand scaffolds were synthesized bearing large aryl (2, 4, 6-Ph3C6H2,
abbreviated Ar) or alkyl (t Bu, adamantyl) flanking groups to afford three new disubstituted …
abbreviated Ar) or alkyl (t Bu, adamantyl) flanking groups to afford three new disubstituted …
Toward the Synthesis of More Reactive S = 2 Non-Heme Oxoiron(IV) Complexes
M Puri, L Que Jr - Accounts of Chemical Research, 2015 - ACS Publications
Conspectus 2003 marked a banner year in the bioinorganic chemistry of mononuclear non-
heme iron enzymes. The first non-heme oxoiron (IV) intermediate (called J) was trapped and …
heme iron enzymes. The first non-heme oxoiron (IV) intermediate (called J) was trapped and …
Exchange-enhanced reactivity in bond activation by metal–oxo enzymes and synthetic reagents
Reactivity principles based on orbital overlap and bonding/antibonding interactions are well
established to describe the reactivity of organic species, and atomic structures are typically …
established to describe the reactivity of organic species, and atomic structures are typically …
Understanding and Breaking Scaling Relations in Single-Site Catalysis: Methane to Methanol Conversion by FeIVO
Computational high-throughput screening is an essential tool for catalyst design, limited
primarily by the efficiency with which accurate predictions can be made. In bulk …
primarily by the efficiency with which accurate predictions can be made. In bulk …
Spinning around in transition-metal chemistry
Conspectus The great diversity and richness of transition metal chemistry, such as the
features of an open d-shell, opened a way to numerous areas of scientific research and …
features of an open d-shell, opened a way to numerous areas of scientific research and …
Mechanism of Oxidation of Ethane to Ethanol at Iron(IV)–Oxo Sites in Magnesium-Diluted Fe2(dobdc)
The catalytic properties of the metal–organic framework Fe2 (dobdc), containing open Fe (II)
sites, include hydroxylation of phenol by pure Fe2 (dobdc) and hydroxylation of ethane by its …
sites, include hydroxylation of phenol by pure Fe2 (dobdc) and hydroxylation of ethane by its …