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Sulfur-based ferroelectric nematic liquid crystals
We report a structure–property relationship in sulfur-based chemical structures for
thermotropic ferroelectric nematic (NF) materials. We synthesized a wide variety of sulfur …
thermotropic ferroelectric nematic (NF) materials. We synthesized a wide variety of sulfur …
Twist-bend nematic liquid crystals based on thioether linkage
Y Arakawa, K Komatsu, H Tsuji - New Journal of Chemistry, 2019 - pubs.rsc.org
We developed twist-bend nematogens based on cyanobiphenyl dimers with thioether or
sulfur linkage, as opposed to the commonly used methylene and ether linkages. Based on …
sulfur linkage, as opposed to the commonly used methylene and ether linkages. Based on …
Supramolecular liquid crystals from the dimer of L‐shaped molecules with tertiary amide end groups
Y Sawatari, Y Shimomura, M Takeuchi, R Iwai… - …, 2024 - Wiley Online Library
Supramolecular liquid crystals (SLCs) are attractive materials for fabricating devices with
new optoelectronic functions. Conventional SLCs are made from hydrogen‐bonded …
new optoelectronic functions. Conventional SLCs are made from hydrogen‐bonded …
Thioether-linked liquid crystal dimers and trimers: The twist-bend nematic phase
Y Arakawa, K Komatsu, S Inui, H Tsuji - Journal of Molecular Structure, 2020 - Elsevier
Systematic synthesis of thioether-linked dimers and trimers was carried out to reveal
molecular designs for inducing mesophases and twist-bend nematic (N TB) phases. A five …
molecular designs for inducing mesophases and twist-bend nematic (N TB) phases. A five …
The effects of alkylthio chains on the properties of symmetric liquid crystal dimers
The synthesis and characterisation of four series of symmetric liquid crystal dimers
containing either alkylthio or alkyloxy terminal chains are reported. The (E, E)-[pentane-1, 5 …
containing either alkylthio or alkyloxy terminal chains are reported. The (E, E)-[pentane-1, 5 …
Ether‐and Thioether‐Linked Naphthalene‐Based Liquid‐Crystal Dimers: Influence of Chalcogen Linkage and Mesogenic‐Arm Symmetry on the Incidence and …
Y Arakawa, Y Ishida, H Tsuji - Chemistry–A European Journal, 2020 - Wiley Online Library
The twist–bend nematic (NTB) phase with a heliconical nanostructure of the local director
generating symmetry breaking by achiral bent‐shaped molecules is a hot topic of current …
generating symmetry breaking by achiral bent‐shaped molecules is a hot topic of current …
The design of liquid crystalline bistolane-based materials with extremely high birefringence
We designed three new bistolanes with alkylsulfanyl groups. A symmetric derivative
contains short terminal methylsulfanyl groups (–SCH3) on both ends, while two asymmetric …
contains short terminal methylsulfanyl groups (–SCH3) on both ends, while two asymmetric …
Methylene-and thioether-linked cyanobiphenyl-based liquid crystal dimers CB n SCB exhibiting room temperature twist-bend nematic phases and glasses
Y Arakawa, K Komatsu, T Shiba, H Tsuji - Materials Advances, 2021 - pubs.rsc.org
The twist-bend nematic (NTB) phase is a new heliconical liquid crystal (LC) phase that is
associated with spontaneous symmetry breaking for achiral bent LC molecules. Herein, we …
associated with spontaneous symmetry breaking for achiral bent LC molecules. Herein, we …
Lateral substituent effects on UV stability of high-birefringence liquid crystals with the diaryl-diacetylene core: DFT/TD-DFT study
R Chen, Z An, W Wang, X Chen, P Chen - Liquid Crystals, 2017 - Taylor & Francis
To study the effect of the lateral substituents on the UV stability of high birefringence liquid
crystals (LCs), computational chemistry was used to examine a series of high birefringence …
crystals (LCs), computational chemistry was used to examine a series of high birefringence …
Phase behaviour of ester-linked cyanobiphenyl dimers and fluorinated analogues: the direct isotropic to twist-bend nematic phase transition
Y Arakawa, K Horita, K Igawa - Liquid Crystals, 2023 - Taylor & Francis
Typically, the twist-bend nematic (NTB) phase appears below the temperature of the
conventional nematic (N) phase. The direct formation of the NTB phase from the isotropic …
conventional nematic (N) phase. The direct formation of the NTB phase from the isotropic …