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Bioorthogonal chemistry for prodrug activation in vivo
Prodrugs have emerged as a major strategy for addressing clinical challenges by improving
drug pharmacokinetics, reducing toxicity, and enhancing treatment efficacy. The emergence …
drug pharmacokinetics, reducing toxicity, and enhancing treatment efficacy. The emergence …
The chemical recycling of polyesters for a circular plastics economy: challenges and emerging opportunities
Whilst plastics have played an instrumental role in human development, growing
environmental concerns have led to increasing public scrutiny and demands for outright …
environmental concerns have led to increasing public scrutiny and demands for outright …
Mechanochemical tools for polymer materials
Mechanochemistry provides a unique approach to investigate macroscopic deformation,
failure and healing of polymer materials. The development of mechanophores–molecular …
failure and healing of polymer materials. The development of mechanophores–molecular …
Force-controlled release of small molecules with a rotaxane actuator
Force-controlled release of small molecules offers great promise for the delivery of drugs
and the release of healing or reporting agents in a medical or materials context,–. In polymer …
and the release of healing or reporting agents in a medical or materials context,–. In polymer …
Covalent mechanochemistry and contemporary polymer network chemistry: A marriage in the making
Over the past 20 years, the field of polymer mechanochemistry has amassed a toolbox of
mechanophores that translate mechanical energy into a variety of functional responses …
mechanophores that translate mechanical energy into a variety of functional responses …
Toughening hydrogels through force-triggered chemical reactions that lengthen polymer strands
The utility and lifetime of materials made from polymer networks, including hydrogels,
depend on their capacity to stretch and resist tearing. In gels and elastomers, those …
depend on their capacity to stretch and resist tearing. In gels and elastomers, those …
Mechanochemical bond scission for the activation of drugs
Pharmaceutical drug therapy is often hindered by issues caused by poor drug selectivity,
including unwanted side effects and drug resistance. Spatial and temporal control over drug …
including unwanted side effects and drug resistance. Spatial and temporal control over drug …
The many flavours of mechanochemistry and its plausible conceptual underpinnings
RT O'Neill, R Boulatov - Nature Reviews Chemistry, 2021 - nature.com
Mechanochemistry describes diverse phenomena in which mechanical load affects
chemical reactivity. The fuzziness of this definition means that it includes processes as …
chemical reactivity. The fuzziness of this definition means that it includes processes as …
100th Anniversary of macromolecular science viewpoint: Toward catalytic chemical recycling of waste (and future) plastics
The current global materials economy has long been inefficient due to unproductive reuse
and recycling efforts. Within the wider materials portfolio, plastics have been revolutionary to …
and recycling efforts. Within the wider materials portfolio, plastics have been revolutionary to …
The role of polymer mechanochemistry in responsive materials and additive manufacturing
MA Ghanem, A Basu, R Behrou, N Boechler… - Nature Reviews …, 2021 - nature.com
The use of mechanical forces to chemically transform polymers dates back decades. In
recent years, the use of mechanochemistry to direct constructive transformations in polymers …
recent years, the use of mechanochemistry to direct constructive transformations in polymers …