Metallaheteroboranes with group 16 elements: Aspects of synthesis, framework and reactivity
Metallaheteroborane clusters containing group-16 elements as cluster constituents were
initially of interest solely for the synthesis of high-nuclearity clusters. However, owing to …
initially of interest solely for the synthesis of high-nuclearity clusters. However, owing to …
Metal-rich metallaboranes: Clusters containing triply and tetra bridging borylene and boride units
Metal-rich metallaborane clusters, having triply and tetra bridging borylenes, and
multicentred boride units are demanding renewed interest because of their diverse reactivity …
multicentred boride units are demanding renewed interest because of their diverse reactivity …
Trimetallic Chalcogenide Species: Synthesis, Structures, and Bonding
In an attempt to isolate boron-containing tri-niobium polychalcogenide species, we have
carried out prolonged thermolysis reactions of [Cp* NbCl4](Cp*= ɳ 5-C5Me5) with four …
carried out prolonged thermolysis reactions of [Cp* NbCl4](Cp*= ɳ 5-C5Me5) with four …
Chalcogen stabilized trimetallic clusters: synthesis, structures, and bonding of [(Cp* M) 3 (E) 6+ m (BH) n](M= Nb or Ta; E= S or Se; m= 0 or 1 or 2; n= 0 or 1)
In an effort to isolate the chalcogen-rich niobium analogue of [(Cp* Ta) 3 (μ-S) 3 (μ3-S) 3BH],
the room temperature reaction of [Cp* NbCl4](Cp*= η5-C5Me5) with Li [BH2S3] was carried …
the room temperature reaction of [Cp* NbCl4](Cp*= η5-C5Me5) with Li [BH2S3] was carried …
Structural and electronic analysis of bimetallic thiolate complexes of group-5 transition metal ions
The chemistry of group-5 transition metals, namely vanadium, niobium, and tantalum
supported by thiolate ligand framework, has been described. Special emphasis has been …
supported by thiolate ligand framework, has been described. Special emphasis has been …
Stabilization of dichalcogenide ligands in the coordination sphere of a ruthenium system
The synthesis, structure and electronic properties of tetraruthenium dichalcogenide
complexes displaying the exclusive coordination mode of dichalcogenide ligands have …
complexes displaying the exclusive coordination mode of dichalcogenide ligands have …
Syntheses, structures, and bonding of boron containing niobium and ruthenium clusters stabilized by chalcogens
In an effort to synthesize niobaheteroboranes and ruthenaheteroboranes, two different
synthetic methods are developed. The reactions of [Cp* NbCl 4](1) with chalcogenaborate …
synthetic methods are developed. The reactions of [Cp* NbCl 4](1) with chalcogenaborate …
Metallaboranes and metallaheteroboranes: An overview of single-cage and condensed polyhedral clusters
C Nandi, K Kar, A Roy, S Ghosh - Advances in Inorganic Chemistry, 2023 - Elsevier
Over time, cluster growth reactions for higher nuclearity clusters transformed into the main
goal in polyhedral metallaborane and metallaheteroborane chemistry. Metallaboranes and …
goal in polyhedral metallaborane and metallaheteroborane chemistry. Metallaboranes and …
Role of Metals and Thiolate Ligands in the Structures and Electronic Properties of Group 5 Bimetallic–Thiolate Complexes
Syntheses, structures, and electronic properties of group 5 metal–thiolate complexes that
exhibit unusual coordination modes of thiolate ligands have been established. Room …
exhibit unusual coordination modes of thiolate ligands have been established. Room …
Manganese Telluride Carbonyl Complexes: Facile Syntheses and Exotic Properties—Reversible Transformations, Hydrogen Generation, Paramagnetic, and …
M Shieh, YH Liu, TS Lin, YC Lin, WK Cheng… - Inorganic …, 2020 - ACS Publications
A novel family of five Mn–Te–CO complexes was prepared via facile syntheses: mono
spirocyclic [Mn4Te (CO) 16] 2–(1), four-membered Mn2Te2 ring-type [Mn2Te2 (CO) 8] 2–(2) …
spirocyclic [Mn4Te (CO) 16] 2–(1), four-membered Mn2Te2 ring-type [Mn2Te2 (CO) 8] 2–(2) …