Synthesis, Characterization, and Reactions of Ruthenium(II), -(III), and -(IV) Complexes with Sterically Demanding 1,2,4-Tri-tert-butylcyclopentadienyl Ligands
R Shimogawa, T Takao, H Suzuki - Organometallics, 2014 - ACS Publications
The reaction of RuCl3· 3H2O with 1, 3, 5-C5 (t Bu) 3H3 afforded a dimeric Ru (III) dichloride
complex,[Cp‡ RuCl (μ-Cl)] 2 (1b; Cp‡= η5-1, 2, 4-C5 (t Bu) 3H2). The treatment of 1b with …
complex,[Cp‡ RuCl (μ-Cl)] 2 (1b; Cp‡= η5-1, 2, 4-C5 (t Bu) 3H2). The treatment of 1b with …
Synthesis of Novel Allene-Coordinated, Phosphido-Bridged Ru2Pt Clusters Involving Enyne to Allene Transformation
Microwave irradiation of a toluene solution of the diyne FcC2C2Ph and Ru3 (CO) 12 yields
the [Ru (CO) 3 (η4-ruthenole)] derivatives 1a–f, which differ in relative positions of the …
the [Ru (CO) 3 (η4-ruthenole)] derivatives 1a–f, which differ in relative positions of the …
Reactivity of 1, 3-ynone in transformation of Ru2–Ru4 clusters: Formation of ruthenoles via tetraruthenium intermediate
J Yang, W Zhang, G Zhang, Z Gao - Journal of Organometallic Chemistry, 2015 - Elsevier
A robust “soft and hard” alkyne ligand, 1, 3-ynone, induced the stepwise transformation of
ruthenium carbonyl clusters. The thermolysis reactions of Ru 3 (CO) 12 (1) with 1-(4 …
ruthenium carbonyl clusters. The thermolysis reactions of Ru 3 (CO) 12 (1) with 1-(4 …
Towards Reagents for Bimetallic Activation Reactions: Polyhydride Complexes with Ru2H3, Ru2ZnH6, and Cu2Ru2H6 Cores
M Plois, R Wolf, W Hujo… - European Journal of …, 2013 - Wiley Online Library
The utility of the fac‐[RuH3 (PR3) 3]–anion (R= Ph, C6H4‐4‐Me) for the preparation of new
oligonuclear transition metal polyhydrides has been examined. The lithium salts [Li (thf) x …
oligonuclear transition metal polyhydrides has been examined. The lithium salts [Li (thf) x …
Vinylidene carbonylation at a manganese–iron complex: A density functional study of mechanism
EAI Shor, VA Nasluzov, AM Shor, AB Antonova… - Journal of …, 2011 - Elsevier
Treating the phenylvinyldene manganese complex Cp (CO) 2MnC1C2HPh, 1, with [Fe (CO)
4] yields the binuclear μ-vinylidene complex Cp (CO) 2MnFe (μ-C1C2HPh)(CO) 4, 2, that …
4] yields the binuclear μ-vinylidene complex Cp (CO) 2MnFe (μ-C1C2HPh)(CO) 4, 2, that …