Understanding MOF flexibility: An analysis focused on pillared layer MOFs as a model system
Flexible porous frameworks are at the forefront of materials research. A unique feature is
their ability to open and close their pores in an adaptive manner induced by chemical and …
their ability to open and close their pores in an adaptive manner induced by chemical and …
Confinement-guided photophysics in MOFs, COFs, and cages
In this review, the dependence of the photophysical response of chromophores in the
confined environments associated with crystalline scaffolds, such as metal–organic …
confined environments associated with crystalline scaffolds, such as metal–organic …
Dual metalation in a two-dimensional covalent organic framework for photocatalytic C–N cross-coupling reactions
Covalent organic frameworks (COFs) are promising hosts in heterogeneous catalysis.
Herein, we report a dual metalation strategy in a single two-dimensional-COF TpBpy for …
Herein, we report a dual metalation strategy in a single two-dimensional-COF TpBpy for …
The chemistry of metal–organic frameworks with face-centered cubic topology
The precise control of molecular building blocks (MBBs) permits access to various types of
tailor-made functional materials. The best example of this is in the assembly of metal …
tailor-made functional materials. The best example of this is in the assembly of metal …
Defect-enabling zirconium-based metal–organic frameworks for energy and environmental remediation applications
This comprehensive review explores the diverse applications of defective zirconium-based
metal–organic frameworks (Zr-MOFs) in energy and environmental remediation. Zr-MOFs …
metal–organic frameworks (Zr-MOFs) in energy and environmental remediation. Zr-MOFs …
Modulation of the Photophysics and Internal Dynamics in a Zr Metal Organic Framework by the Inclusion of Fluorinated Guests
Herein, we report the precise modulation of the fast rotational dynamics in the MOF UiO-68
by the adsorption of 1, 4-tetrafluorobenzoquinone (TFBQ) or hexafluorobenzene (F 6 Bz). In …
by the adsorption of 1, 4-tetrafluorobenzoquinone (TFBQ) or hexafluorobenzene (F 6 Bz). In …
Interplay of structural dynamics and electronic effects in an engineered assembly of pentacene in a metal–organic framework
Charge carrier mobility is an important figure of merit to evaluate organic semiconductor
(OSC) materials. In aggregated OSCs, this quantity is determined by inter-chromophoric …
(OSC) materials. In aggregated OSCs, this quantity is determined by inter-chromophoric …
Insights into the interaction between immobilized biocatalysts and metal–organic frameworks: a case study of PCN-333
W Yang, W Liang, LA O'Dell, HD Toop, N Maddigan… - JACS Au, 2021 - ACS Publications
The immobilization of enzymes in metal–organic frameworks (MOFs) with preserved
biofunctionality paves a promising way to solve problems regarding the stability and …
biofunctionality paves a promising way to solve problems regarding the stability and …
Structural flexibility in crystalline coordination polymers: a journey along the underlying free energy landscape
Crystalline coordination polymers are a chemically diverse material platform that provide
control over network geometry and chemical interactions, harbouring a wealth of …
control over network geometry and chemical interactions, harbouring a wealth of …
Vegard's law in multivariate libraries of porous interpenetrated zirconia organic frameworks
JI Furst, JT Bryant, KR Langlois, SD Myers… - Inorganic Chemistry …, 2024 - pubs.rsc.org
In this contribution we demonstrate that metal–organic frameworks (MOFs) with suitable
underlying topological structure are amenable for the preparation of MOF-based …
underlying topological structure are amenable for the preparation of MOF-based …