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The halogen bond
The halogen bond occurs when there is evidence of a net attractive interaction between an
electrophilic region associated with a halogen atom in a molecular entity and a nucleophilic …
electrophilic region associated with a halogen atom in a molecular entity and a nucleophilic …
Halogen bonding in supramolecular chemistry
LC Gilday, SW Robinson, TA Barendt… - Chemical …, 2015 - ACS Publications
Supramolecular chemistry is “the chemistry of the intermolecular bond, covering the
structures and functions of the entities formed by association of two or more chemical …
structures and functions of the entities formed by association of two or more chemical …
Halogen bonding, chalcogen bonding, pnictogen bonding, tetrel bonding: origins, current status and discussion
L Brammer - Faraday Discussions, 2017 - pubs.rsc.org
The role of the closing lecture in a Faraday Discussion is to summarise the contributions
made to the Discussion over the course of the meeting and in so doing capture the main …
made to the Discussion over the course of the meeting and in so doing capture the main …
Confronting Sulfur Electrode Passivation and Li Metal Electrode Degradation in Lithium‐Sulfur Batteries Using Thiocyanate Anion
Salt anions with a high donor number (DN) enable high sulfur utilization in lithium‐sulfur (Li‐
S) batteries by inducing three‐dimensional (3D) Li2S growth. However, their insufficient …
S) batteries by inducing three‐dimensional (3D) Li2S growth. However, their insufficient …
Unravelling the potential of sigma hole-assisted co-crystallization: Highlighting recent developments
In the past several decades, the field of cocrystal engineering has developed into a vital
research topic in supramolecular chemistry, holding the foremost scope in crystal …
research topic in supramolecular chemistry, holding the foremost scope in crystal …
Diaryliodonium as a double σ-hole donor: The dichotomy of thiocyanate halogen bonding provides divergent solid state arylation by diaryliodonium cations
X-ray crystallography data revealed the dichotomy of thiocyanate-involving noncovalent
interactions in [Ar1Ar2I](SCN), as reflected in the generation of two types of supramolecular …
interactions in [Ar1Ar2I](SCN), as reflected in the generation of two types of supramolecular …
Comparison of the DFT-SAPT and canonical EDA schemes for the energy decomposition of various types of noncovalent interactions
Interaction energies computed with density functional theory can be divided into physically
meaningful components by symmetry-adapted perturbation theory (DFT-SAPT) or the …
meaningful components by symmetry-adapted perturbation theory (DFT-SAPT) or the …
Halogen bonding in the co-crystallization of potentially ditopic diiodotetrafluorobenzene: a powerful tool for constructing multicomponent supramolecular assemblies
Halogen bonding is emerging as a significant driving force for supramolecular self-assembly
and has aroused great interest during the last two decades. Among the various halogen …
and has aroused great interest during the last two decades. Among the various halogen …
Electron belt-to-σ-hole switch of noncovalently bound iodine (I) atoms in dithiocarbamate metal complexes
Co-crystallization of dithiocarbamate complexes [MII (S2CNEt2) 2](M= Cu 1, Ni 2, Pd 3, Pt 4)
and 1, 3, 5-triiodotrifluorobenzene (FIB) gives an isomorphic series of (1–4)· 2FIB co-crystals …
and 1, 3, 5-triiodotrifluorobenzene (FIB) gives an isomorphic series of (1–4)· 2FIB co-crystals …
Coordination of anions by noncovalently bonded σ-hole ligands
Research on σ-hole interactions that include halogen, chalcogen, pnicogen, and tetrel
bonding has been accelerating in recent years. These cousins of the H-bond have many …
bonding has been accelerating in recent years. These cousins of the H-bond have many …