Non-adiabatic excited-state molecular dynamics: Theory and applications for modeling photophysics in extended molecular materials

TR Nelson, AJ White, JA Bjorgaard, AE Sifain… - Chemical …, 2020 - ACS Publications
Optically active molecular materials, such as organic conjugated polymers and biological
systems, are characterized by strong coupling between electronic and vibrational degrees of …

Computational approaches for organic semiconductors: from chemical and physical understanding to predicting new materials

V Bhat, CP Callaway, C Risko - Chemical Reviews, 2023 - ACS Publications
While a complete understanding of organic semiconductor (OSC) design principles remains
elusive, computational methods─ ranging from techniques based in classical and quantum …

Ab Initio Multiple Spawning nonadiabatic dynamics with different CASPT2 flavors: A fully open-source PySpawn/OpenMolcas interface

LM Ibele, A Memhood, BG Levine… - Journal of Chemical …, 2024 - ACS Publications
We introduce an interface between PySpawn, a simulation package to run ab initio multiple
spawning (AIMS) nonadiabatic dynamics, and OpenMolcas, a software package to perform …

NEXMD software package for nonadiabatic excited state molecular dynamics simulations

W Malone, B Nebgen, A White, Y Zhang… - Journal of Chemical …, 2020 - ACS Publications
We present a versatile new code released for open community use, the nonadiabatic excited
state molecular dynamics (NEXMD) package. This software aims to simulate nonadiabatic …

Nexmd v2. 0 software package for nonadiabatic excited state molecular dynamics simulations

VM Freixas, W Malone, X Li, H Song… - Journal of Chemical …, 2023 - ACS Publications
We present NEXMD version 2.0, the second release of the NEXMD (Nonadiabatic EXcited-
state Molecular Dynamics) software package. Across a variety of new features, NEXMD v2. 0 …

Nonadiabatic dynamics algorithms with only potential energies and gradients: Curvature-driven coherent switching with decay of mixing and curvature-driven …

Y Shu, L Zhang, X Chen, S Sun, Y Huang… - Journal of Chemical …, 2022 - ACS Publications
Direct dynamics by mixed quantum-classical nonadiabatic methods is an important tool for
understanding processes involving multiple electronic states. Very often, the computational …

A simple phase correction makes a big difference in nonadiabatic molecular dynamics

AV Akimov - The journal of physical chemistry letters, 2018 - ACS Publications
The outcomes of nonadiabatic molecular dynamics (NA-MD) calculations are modulated by
the parameters entering the time-dependent Schrödinger equation (TD-SE). The adiabatic …

Photochemical spin-state control of binding configuration for tailoring organic color center emission in carbon nanotubes

Y Zheng, Y Han, BM Weight, Z Lin, BJ Gifford… - Nature …, 2022 - nature.com
Incorporating fluorescent quantum defects in the sidewalls of semiconducting single-wall
carbon nanotubes (SWCNTs) through chemical reaction is an emerging route to predictably …

All-atom nonadiabatic semiclassical map** dynamics for photoinduced charge transfer of organic photovoltaic molecules in explicit solvents

Z Hu, X Sun - Journal of Chemical Theory and Computation, 2022 - ACS Publications
Direct all-atom simulation of nonadiabatic dynamics in disordered condensed phases like
liquid solutions and amorphous solids has been challenging. The first all-atom simulation of …

Quantum and semiclassical dynamical studies of nonadiabatic processes in solution: achievements and perspectives

F Santoro, JA Green, L Martinez-Fernandez… - Physical Chemistry …, 2021 - pubs.rsc.org
We concisely review the main methodological approaches to model nonadiabatic dynamics
in isotropic solutions and their applications. Three general classes of models are identified …