Manipulating matter by strong coupling to vacuum fields
BACKGROUND One of the most important phenomena in cavity quantum electrodynamics
(cQED) is the so-called strong coupling regime, which appears when the interaction …
(cQED) is the so-called strong coupling regime, which appears when the interaction …
Theoretical advances in polariton chemistry and molecular cavity quantum electrodynamics
When molecules are coupled to an optical cavity, new light–matter hybrid states, so-called
polaritons, are formed due to quantum light–matter interactions. With the experimental …
polaritons, are formed due to quantum light–matter interactions. With the experimental …
The rise and current status of polaritonic photochemistry and photophysics
The interaction between molecular electronic transitions and electromagnetic fields can be
enlarged to the point where distinct hybrid light–matter states, polaritons, emerge. The …
enlarged to the point where distinct hybrid light–matter states, polaritons, emerge. The …
Modification of ground-state chemical reactivity via light–matter coherence in infrared cavities
Reaction-rate modifications for chemical processes due to strong coupling between reactant
molecular vibrations and the cavity vacuum have been reported; however, no currently …
molecular vibrations and the cavity vacuum have been reported; however, no currently …
Chemistry under vibrational strong coupling
Over the past decade, the possibility of manipulating chemistry and material properties using
hybrid light–matter states has stimulated considerable interest. Hybrid light–matter states …
hybrid light–matter states has stimulated considerable interest. Hybrid light–matter states …
Quantum dynamical effects of vibrational strong coupling in chemical reactivity
Recent experiments suggest that ground state chemical reactivity can be modified when
placing molecular systems inside infrared cavities where molecular vibrations are strongly …
placing molecular systems inside infrared cavities where molecular vibrations are strongly …
Understanding polaritonic chemistry from ab initio quantum electrodynamics
In this review, we present the theoretical foundations and first-principles frameworks to
describe quantum matter within quantum electrodynamics (QED) in the low-energy regime …
describe quantum matter within quantum electrodynamics (QED) in the low-energy regime …
Control, modulation, and analytical descriptions of vibrational strong coupling
Here, we review the design of optical cavities, transient and modulated responses, and
theoretical models relevant to vibrational strong coupling (VSC). While planar Fabry–Perot …
theoretical models relevant to vibrational strong coupling (VSC). While planar Fabry–Perot …
Hybrid light–matter states in a molecular and material science perspective
TW Ebbesen - Accounts of chemical research, 2016 - ACS Publications
Conspectus The notion that light and matter states can be hybridized the way s and p
orbitals are mixed is a concept that is not familiar to most chemists and material scientists …
orbitals are mixed is a concept that is not familiar to most chemists and material scientists …
Molecular chemistry in cavity strong coupling
The coherent exchange of energy between materials and optical fields leads to strong light–
matter interactions and so-called polaritonic states with intriguing properties, halfway …
matter interactions and so-called polaritonic states with intriguing properties, halfway …