Electrochemistry of actinides and fission products in molten salts—Data review

J Zhang - Journal of Nuclear Materials, 2014 - Elsevier
The thermodynamic and electrochemical properties of actinides and fission products in the
molten salt determine the pyroprocessing separation performance. Extensive measurements …

Insights into the effects of fluoride anions on the electrochemical behavior and solution structure of trivalent samarium in LiCl-KCl molten salt

S Jiang, C Ye, Y Liu, D Yang, L Wang, Y Liu, Y Zhong… - Electrochimica …, 2023 - Elsevier
Understanding the correlation between the electrochemical behavior and solution structure
of lanthanides in molten salt is essential to improve the efficiency of electrorefining based …

Large-scale preparation of graphene by high temperature insertion of hydrogen into graphite

AR Kamali, DJ Fray - Nanoscale, 2015 - pubs.rsc.org
Experimental evidence for high temperature diffusion of hydrogen into the interlayer space
of graphite is provided. This process is discussed as a possible method for the rapid …

Natural convection in molten salt electrochemistry

J Ge, B Cai, F Zhu, Y Gao, X Wang… - The Journal of …, 2023 - ACS Publications
Molten salt electrochemistry has been widely used in many fields, especially for metal
extraction/refinement. The understanding of mass transfer in molten salts under harsh …

Selective extraction of Sm from LiCl-KCl molten salt into wasteforms via liquid bismuth

H Zhang, Q Du, X Du, Z Xu, S Guo, W Zhou - Separation and Purification …, 2023 - Elsevier
The electrorefining of spent nuclear fuels in a molten LiCl-KCl salt electrolyte recovers the
valuable actinides but also releases radioactive fission products in the salt. To minimize the …

Electrochemical deoxidation of titanium scrap in MgCl2-HoCl3 system

L Kong, T Ouchi, C Zheng… - Journal of the …, 2019 - iopscience.iop.org
A novel electrochemical deoxidation process for Ti in the magnesium chloride− holmium
chloride (MgCl 2− HoCl 3) system was developed. The reaction mechanism was proposed …

Application of liquid Ga-Pb cathode for selective separation of samarium fission products from molten alkali metal chlorides

H Zhang, Q Liu, A Novoselova, V Smolenski… - Separation and …, 2024 - Elsevier
The efficient separation of the rare earth element Sm from spent nuclear fuel is of strategic
importance for the nuclear industries. This study explored the feasibility of a novel liquid Ga …

Evaluation of the local structure and electrochemical behavior in the LiCl-KCl-SmCl3 melt

J Zhao, Z Liu, W Liang, G Lu - Journal of Molecular Liquids, 2022 - Elsevier
This present work evaluates the local structure and electrochemical behavior of the LiCl-KCl-
SmCl 3 melt to facilitate the efficient reprocessing of spent nuclear fuel (SNF). At 723 K, the …

Electrochemical behavior and underpotential deposition of Sm on reactive electrodes (Al, Ni, Cu and Zn) in a LiCl-KCl melt

T Yin, L Chen, Y Xue, Y Zheng, X Wang, Y Yan… - International Journal of …, 2020 - Springer
Sm extraction from a LiCl-KCl melt was carried out by forming alloys on various electrodes,
including Al, Ni, Cu, and liquid Zn, and the electrochemical behaviors of the resultant metal …

Electrochemical and Spectroscopic Properties of Europium in AlCl3-NaCl Melts

JZ Chen, YK Zhong, YL Liu, M Li… - Journal of The …, 2023 - iopscience.iop.org
The physicochemical properties of Eu cations in AlCl 3-NaCl melts have been studied for the
purpose of spent nuclear fuel recycling via electrochemical and spectroscopic methods. Eu …