We demonstrate that collective vibrational strong coupling of molecules in thermal
equilibrium can give rise to significant local electronic polarizations in the thermodynamic …

We derive an analytic expression of the non-equilibrium Fermi's golden rule (NE-FGR)
expression for a Holstein–Tavis–Cumming Hamiltonian, a universal model for many …

Reports of altered chemical phenomena under vibrational strong coupling, including
reaction rates, product distributions, intermolecular forces, and cavity-mediated vibrational …

Significant debate surrounds the origin of nonlinear optical responses from cavity-coupled
molecular vibrations. Several groups, including our own, have previously assigned portions …

Recent experiments in polariton chemistry indicate that reaction rates can be significantly
enhanced or suppressed inside an optical cavity. One possible explanation for the rate …

In this work, we investigate anharmonic vibrational polaritons formed due to strong light–
matter interactions in an optical cavity between radiation modes and anharmonic vibrations …

Recent experiments have demonstrated that it is possible to modify ground-state chemical
reactivities by placing an ensemble of molecules in an optical microcavity through resonant …

The emerging interdisciplinary research field of vibro-polaritonic chemistry exploits the
concept of vibrational strong coupling (VSC) to shape chemical reactivity and molecular …

We discuss theoretical methods with which the effects of static, homogenous,
electromagnetic fields can be determined for systems that are extended and in the ultimate …