The halogen bond
The halogen bond occurs when there is evidence of a net attractive interaction between an
electrophilic region associated with a halogen atom in a molecular entity and a nucleophilic …
electrophilic region associated with a halogen atom in a molecular entity and a nucleophilic …
The bright future of unconventional σ/π‐hole interactions
Non‐covalent interactions play a crucial role in (supramolecular) chemistry and much of
biology. Supramolecular forces can indeed determine the structure and function of a host …
biology. Supramolecular forces can indeed determine the structure and function of a host …
A million crystal structures: The whole is greater than the sum of its parts
R Taylor, PA Wood - Chemical reviews, 2019 - ACS Publications
The founding in 1965 of what is now called the Cambridge Structural Database (CSD) has
reaped dividends in numerous and diverse areas of chemical research. Each of the million …
reaped dividends in numerous and diverse areas of chemical research. Each of the million …
Crystal engineering strategies towards halogen-bonded metal–organic multi-component solids: Salts, cocrystals and salt cocrystals
Over the past several decades, halogen bonding has become a standard 'tool'in
supramolecular chemistry and particularly in crystal engineering. Traditionally, the study of …
supramolecular chemistry and particularly in crystal engineering. Traditionally, the study of …
Halogen-bonded cocrystals as optical materials: Next-generation control over light–matter interactions
This review summarizes the recent advances in utilizing halogen bond-driven cocrystal
formation as a design element in the creation of optical or photoresponsive materials …
formation as a design element in the creation of optical or photoresponsive materials …
Halogen-bonded cocrystallization with phosphorus, arsenic and antimony acceptors
The formation of non-covalent directional interactions, such as hydrogen or halogen bonds,
is a central concept of materials design, which hinges on using small compact atoms of the …
is a central concept of materials design, which hinges on using small compact atoms of the …
C2-Symmetric Cyclic Selenium-Catalyzed Enantioselective Bromoaminocyclization
F Chen, CK Tan, YY Yeung - Journal of the American Chemical …, 2013 - ACS Publications
A catalytic asymmetric bromocyclization of trisubstituted olefinic amides that uses a C 2-
symmetric mannitol-derived cyclic selenium catalyst and a stoichiometric amount of N …
symmetric mannitol-derived cyclic selenium catalyst and a stoichiometric amount of N …
Halogen bonding in cadmium (ii) MOFs: its influence on the structure and on the nitroaldol reaction in aqueous medium
A solvothermal reaction of Cd (II) with the dicarboxyl-functionalized arylhydrazone pro-
ligands, 5-(2-(2, 4, 6-trioxotetrahydro-pyrimidin-5 (2H)-ylidene) hydrazineyl) isophthalic acid …
ligands, 5-(2-(2, 4, 6-trioxotetrahydro-pyrimidin-5 (2H)-ylidene) hydrazineyl) isophthalic acid …
Halogen bonding with carbon: directional assembly of non-derivatised aromatic carbon systems into robust supramolecular ladder architectures
Carbon, although the central element in organic chemistry, has been traditionally neglected
as a target for directional supramolecular interactions. The design of supramolecular …
as a target for directional supramolecular interactions. The design of supramolecular …
Halogen bonding in the co-crystallization of potentially ditopic diiodotetrafluorobenzene: a powerful tool for constructing multicomponent supramolecular assemblies
Halogen bonding is emerging as a significant driving force for supramolecular self-assembly
and has aroused great interest during the last two decades. Among the various halogen …
and has aroused great interest during the last two decades. Among the various halogen …