Chiral catalysts immobilized on achiral polymers: effect of the polymer support on the performance of the catalyst
B Altava, MI Burguete, E García-Verdugo… - Chemical Society …, 2018 - pubs.rsc.org
Positive effects of the polymeric support on the performance of supported chiral catalysts, in
terms of activity, stability and selectivity–enantioselectivity, have been reported when the …
terms of activity, stability and selectivity–enantioselectivity, have been reported when the …
Synthesis and Applications of Organic Borazine Materials
The past decade has marked a renewed interest in borazines and BN‐doped polycyclic
aromatic hydrocarbons. This is predominantly because of new advances that have …
aromatic hydrocarbons. This is predominantly because of new advances that have …
Tailor-Made POLITAG-Pd0 Catalyst for the Low-Loading Mizoroki–Heck Reaction in γ-Valerolactone as a Safe Reaction Medium
In this contribution, we have reported our study on the fine-tuned design and synthesis of
new POLITAGs-Pd0 (POLymeric Ionic TAG) catalytic systems with the intention of defining …
new POLITAGs-Pd0 (POLymeric Ionic TAG) catalytic systems with the intention of defining …
Recent advances in sulfonated resin catalysts for efficient biodiesel and bio-derived additives production
The drive toward greener process chemistry has stimulated the development of strong solid
acids to replace traditional catalysts for efficient biodiesel production from free fatty acid …
acids to replace traditional catalysts for efficient biodiesel production from free fatty acid …
A tailored polymeric cationic tag–anionic Pd (II) complex as a catalyst for the low-leaching Heck–Mizoroki coupling in flow and in biomass-derived GVL
The [PdCl4] 2− palladium complex has been immobilized on a polystyrene-type resin
loaded with pincer-type imidazolium ionic tag binding sites. The catalytic system (Pd (II) …
loaded with pincer-type imidazolium ionic tag binding sites. The catalytic system (Pd (II) …
A continuous flow approach for the C–H functionalization of 1, 2, 3-triazoles in γ-valerolactone as a biomass-derived medium
Herein we report an efficient procedure for the C–H functionalization of 1, 2, 3-triazoles in a
continuous flow regime applied to a variety of functionalities and to the inter-or …
continuous flow regime applied to a variety of functionalities and to the inter-or …
Polymer-supported bis-1, 2, 4-triazolium ionic tag framework for an efficient Pd (0) catalytic system in biomass derived γ-valerolactone
A resin-bound 1, 2, 4-triazolium ionic tag has been used as support for the preparation of
solid palladium nanoparticles (Pd (0)-POLI-TAG-Pd). Owing to the pincer-type architecture of …
solid palladium nanoparticles (Pd (0)-POLI-TAG-Pd). Owing to the pincer-type architecture of …
A heterogeneous and recoverable palladium catalyst to access the regioselective C–H alkenylation of quinoline N-oxides
Herein, we disclose the first C-2-selective C–H alkenylation of quinoline N-oxides catalyzed
using a heterogeneous palladium catalyst. The protocol does not require the use of an …
using a heterogeneous palladium catalyst. The protocol does not require the use of an …
C(sp3)−H Arylation Promoted by a Heterogeneous Palladium‐N‐Heterocyclic Carbene Complex in Batch and Continuous Flow
A heterogeneous reusable palladium (II)‐bis (N‐heterocyclic carbene) catalyst was
prepared and shown to catalyze the intramolecular C (sp3)− H activation/cyclization of N …
prepared and shown to catalyze the intramolecular C (sp3)− H activation/cyclization of N …
Continuous flow synthesis of 1, 4-disubstituted 1, 2, 3-triazoles via consecutive β-azidation of α, β-unsaturated carbonyl compounds and CuAAC reactions
We herein report a multi-step flow protocol for the synthesis of 1, 4-disubstituted 1, 2, 3-
triazoles starting from α, β-unsaturated carbonyls. Best results, both in terms of chemical …
triazoles starting from α, β-unsaturated carbonyls. Best results, both in terms of chemical …