Molecular cavity for catalysis and formation of metal nanoparticles for use in catalysis

R Saha, B Mondal, PS Mukherjee - Chemical Reviews, 2022 - ACS Publications
The employment of weak intermolecular interactions in supramolecular chemistry offers an
alternative approach to project artificial chemical environments like the active sites of …

Advances in supramolecular host-mediated reactivity

M Morimoto, SM Bierschenk, KT **a, RG Bergman… - Nature Catalysis, 2020 - nature.com
Since the trailblazing discoveries of Lehn, Cram and Pedersen, supramolecular chemistry
has established itself as a cornerstone of organic chemistry. Supramolecular hosts offer …

Picking the lock of coordination cage catalysis

TK Piskorz, V Martí-Centelles, RL Spicer, F Duarte… - Chemical …, 2023 - pubs.rsc.org
The design principles of metallo-organic assembly reactions have facilitated access to
hundreds of coordination cages of varying size and shape. Many of these assemblies …

Photoswitchable catalysis by a self-assembled molecular cage

RG DiNardi, S Rasheed, SS Capomolla… - Journal of the …, 2024 - ACS Publications
A heteroleptic [Pd2L2L'2] 4+ coordination cage containing a photoswitchable azobenzene-
derived ligand catalyzes the Michael addition reaction between methyl vinyl ketone and …

Molecular engineering of confined space in metal–organic cages

JEM Lewis - Chemical Communications, 2022 - pubs.rsc.org
Metal–organic cages (MOCs) have become an intensely studied class of abiotic host
molecules. This is due to the ability to generate a myriad of polyhedral architectures from …

Catalysis within coordination cages

Y Xue, X Hang, J Ding, B Li, R Zhu, H Pang… - Coordination Chemistry …, 2021 - Elsevier
Coordination cages with well-defined cavities have attracted sustained attention for their
applications in many fields, including host-guest chemistry, molecular recognition, and …

A Redox-Active Supramolecular Fe4L6 Cage Based on Organic Vertices with Acid–Base-Dependent Charge Tunability for Dehydrogenation Catalysis

YL Lu, JQ Song, YH Qin, J Guo, YH Huang… - Journal of the …, 2022 - ACS Publications
Supramolecular cage chemistry is of lasting interest because, as artificial blueprints of
natural enzymes, the self-assembled cage structures not only provide substrate-hosting …

Hexaphenylbenzene‐based deep blue‐emissive metallacages as donors for light‐harvesting systems

H Liu, Z Zhang, C Mu, L Ma, H Yuan… - Angewandte Chemie …, 2022 - Wiley Online Library
We herein report the preparation of a series of hexaphenylbenzene (HPB)‐based deep blue‐
emissive metallacages via multicomponent coordination‐driven self‐assembly. These …

Coordination-assembled water-soluble anionic lanthanide organic polyhedra for luminescent labeling and magnetic resonance imaging

Z Wang, L He, B Liu, LP Zhou, LX Cai… - Journal of the …, 2020 - ACS Publications
Lanthanide-containing functional complexes have found a variety of applications in
materials science and biomedicine because of their unique electroptical and magnetic …

Recent advances and perspectives on supramolecular radical cages

B Huang, L Mao, X Shi, HB Yang - Chemical Science, 2021 - pubs.rsc.org
Supramolecular radical chemistry has been emerging as a cutting-edge interdisciplinary
field of traditional supramolecular chemistry and radical chemistry in recent years. The …