Click chemistry is a conceptual strategy to rapidly synthesize and discover functional
molecules. Sulfur fluoride exchange (SuFEx) is a click reaction that has revolutionized …

Sulfur fluoride exchange (SuFEx), a new generation of click chemistry, was first presented by
Sharpless, Dong and co-workers in 2014. Owing to the high stability and yet efficient …

Sulfur (VI) fluoride exchange (SuFEx) gives rise to a plethora of high-valent sulfur linkages;
however, the availability of (aliphatic) sulfonyl fluoride manifolds lag behind, owing to the …

A practical electrochemically driven method for fluorosulfonylation of both aryl and alkyl
thianthrenium salts has been disclosed. The strategy does not need external redox reagents …

A practical electrochemical strategy for the direct synthesis of arenesulfonyl fluorides from
industrial feedstock nitroarenes is described. The key to success lies in using a cheap ionic …

Sulfur (VI)‐fluoride exchange linkage as a next generation of click chemistry was introduced
by Sharpless and coworkers in 2014. Distinguished from CuAAC, the SuFEx reaction …

An electroreductive strategy for radical hydroxyl fluorosulfonylation of alkenes with sulfuryl
chlorofluoride and molecular oxygen from air is described. This mild protocol displays …

Sulfonyl and sulfonimidoyl fluorides are versatile substrates in organic synthesis and
medicinal chemistry. However, they have been exclusively used as S (VI)+ electrophiles for …

Although the transition metal-catalyzed radical fluorine atom transfer (FAT) strategy has
emerged as a powerful tool for the construction of C–F bonds, to our knowledge, this …

Recently, the introduction of fluorosulfonyl (− SO2F) groups have attracted considerable
research interests, as this moiety could often afford enhanced activities and new functions in …