[HTML][HTML] High resolution infrared spectroscopy in support of ozone atmospheric monitoring and validation of the potential energy function

A Barbe, S Mikhailenko, E Starikova, V Tyuterev - Molecules, 2022 - mdpi.com
The first part of this review is a brief reminder of general information concerning atmospheric
ozone, particularly related to its formation, destruction, observations of its decrease in the …

Single-and multireference electronic structure calculations for constructing potential energy surfaces

R Dawes, SA Ndengué - International Reviews in Physical …, 2016 - Taylor & Francis
Recent developments in single and multireference electronic structure methods and the
approaches suitable to generate ab initio data that may be employed in the construction of …

Localized and delocalized bound states of the main isotopologue 48 O 3 and of 18 O-enriched 50 O 3 isotopomers of the ozone molecule near the dissociation …

V Kokoouline, D Lapierre, A Alijah… - Physical Chemistry …, 2020 - pubs.rsc.org
Knowledge of highly excited rovibrational states of ozone isotopologues is of key importance
for modelling the dynamics of exchange reactions, for understanding longstanding problems …

Detection and assignment of ozone bands near 95% of the dissociation threshold: Ultrasensitive experiments for probing potential energy function and vibrational …

S Vasilchenko, A Barbe, E Starikova, S Kassi… - Physical Review A, 2020 - APS
Ozone formation and depletion play a key role in various physical and chemical atmospheric
processes which remain to be understood in more detail. The modeling of such phenomena …

[HTML][HTML] Perspective: Accurate ro-vibrational calculations on small molecules

J Tennyson - The Journal of Chemical Physics, 2016 - pubs.aip.org
In what has been described as the fourth age of quantum chemistry, variational nuclear
motion programs are now routinely being used to obtain the vibration-rotation levels and …

The Role of Ozone Vibrational Resonances in the Isotope Exchange Reaction 16O16O + 18O → 18O16O + 16O: The Time-Dependent Picture

CH Yuen, D Lapierre, F Gatti… - The Journal of …, 2019 - ACS Publications
We consider the time-dependent dynamics of the isotope exchange reaction in collisions
between an oxygen molecule and an oxygen atom: 16O16O+ 18O→ 16O18O+ 16O. A …

Calculation of molecular vibrational spectra on a quantum annealer

A Teplukhin, BK Kendrick… - Journal of chemical theory …, 2019 - ACS Publications
Until recently molecular energy calculations using quantum computing hardware have been
limited to gate-based quantum computers. In this paper, a new methodology is presented to …

Lifetimes and wave functions of ozone metastable vibrational states near the dissociation limit in a full-symmetry approach

D Lapierre, A Alijah, R Kochanov, V Kokoouline… - Physical Review A, 2016 - APS
Energies and lifetimes (widths) of vibrational states above the lowest dissociation limit of O 3
16 were determined using a previously developed efficient approach, which combines …

Towards the intensity consistency of the ozone bands in the infrared range: Ab initio corrections to the S&MPO database

V Tyuterev, A Barbe, S Mikhailenko, E Starikova… - Journal of Quantitative …, 2021 - Elsevier
Accurate knowledge of line parameters, and particularly line intensities is of primary
importance for satellite, ground based and balloon measurements of the ozone …

Long-range ab initio potential energy surface for the ground electronic state of the ozone molecule with the accurate dissociation asymptote

O Egorov, RV Kochanov, V Tyuterev… - Chemical Physics …, 2023 - Elsevier
In this work an excellent agreement was achieved between the empirical (9230.08±4.85
cm− 1) and theoretical (9230.70 cm− 1) values of the first dissociation limit (D e) of O 3. Ab …