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Metal‐based electrocatalysts for methanol electro‐oxidation: progress, opportunities, and challenges
Direct methanol fuel cells (DMFCs) are among the most promising portable power supplies
because of their unique advantages, including high energy density/mobility of liquid fuels …
because of their unique advantages, including high energy density/mobility of liquid fuels …
Theoretical means for searching bimetallic alloys as anode electrocatalysts for direct liquid-feed fuel cells
UB Demirci - Journal of Power Sources, 2007 - Elsevier
The present paper reviews the best anode electrocatalysts, mainly the alloys, which have
been tested in direct liquid-feed fuel cells fed with methanol, ethanol or formic acid. It …
been tested in direct liquid-feed fuel cells fed with methanol, ethanol or formic acid. It …
Selective methanol‐to‐formate electrocatalytic conversion on branched nickel carbide
A methanol economy will be favored by the availability of low‐cost catalysts able to
selectively oxidize methanol to formate. This selective oxidation would allow extraction of the …
selectively oxidize methanol to formate. This selective oxidation would allow extraction of the …
Formate, an active intermediate for direct oxidation of methanol on Pt electrode
YX Chen, A Miki, S Ye, H Sakai… - Journal of the American …, 2003 - ACS Publications
The electro-oxidation of methanol on a Pt thin film electrode in acidic solution has been
investigated by in situ surface-enhanced IR absorption spectroscopy. A new IR peak is …
investigated by in situ surface-enhanced IR absorption spectroscopy. A new IR peak is …
A first principles comparison of the mechanism and site requirements for the electrocatalytic oxidation of methanol and formic acid over Pt
First principles density functional theoretical calculations were carried out to examine and
compare the reaction paths and ensembles for the electrocatalytic oxidation of methanol and …
compare the reaction paths and ensembles for the electrocatalytic oxidation of methanol and …
Graphite nanofibers as an electrode for fuel cell applications
CA Bessel, K Laubernds, NM Rodriguez… - The Journal of …, 2001 - ACS Publications
The potential of graphite nanofiber supported platinum catalysts as an electrode for fuel cell
applications was investigated using the electrochemical oxidation of methanol at 40° C as a …
applications was investigated using the electrochemical oxidation of methanol at 40° C as a …
Noble metal-free hydrazine fuel cell catalysts: EPOC effect in competing chemical and electrochemical reaction pathways
We report the discovery of a highly active Ni− Co alloy electrocatalyst for the oxidation of
hydrazine (N2H4) and provide evidence for competing electrochemical (faradaic) and …
hydrazine (N2H4) and provide evidence for competing electrochemical (faradaic) and …
Electrochemical oxidation of ammonia on nickel oxide nanoparticles
Abstract NiO and NiO–TiO 2 nano-catalysts were synthetized using solution combustion
synthesis (SCS) method and tested toward ammonia oxidation in synthetic and real …
synthesis (SCS) method and tested toward ammonia oxidation in synthetic and real …
Structure sensitivity of methanol electrooxidation pathways on platinum: an on-line electrochemical mass spectrometry study
THM Housmans, AH Wonders… - The Journal of Physical …, 2006 - ACS Publications
By monitoring the mass fractions of CO2 (m/z 44) and methylformate (m/z 60, formed from
CH3OH+ HCOOH) with on-line electrochemical mass spectrometry (OLEMS), the selectivity …
CH3OH+ HCOOH) with on-line electrochemical mass spectrometry (OLEMS), the selectivity …
Mechanisms of methanol decomposition on platinum: A combined experimental and ab initio approach
D Cao, GQ Lu, A Wieckowski… - The Journal of …, 2005 - ACS Publications
The dual path mechanism for methanol decomposition on well-defined low Miller index
platinum single crystal planes, Pt (111), Pt (110), and Pt (100), was studied using a …
platinum single crystal planes, Pt (111), Pt (110), and Pt (100), was studied using a …