In the past decades there has been a dramatic increase in the demand for enantiopure
compounds for fine-chemicals (ie, agrochemicals and pharmaceuticals) and material …

Despite the impressive progress achieved in asymmetric catalysis during the last decade, an
increasing number of new catalysts, ligands, and applications are reported every year to …

Catalytic asymmetric CC bond-forming reactions using organometallic reagents are among
the most important of organic transformations. 1 Frequently, these transformations are key …

Phosphine−Phosphinite and Phosphine−Phosphite Ligands: Preparation and Applications in
Asymmetric Catalysis | Chemical Reviews ACS ACS Publications C&EN CAS Find my institution …

A comprehensive overview of recent literature from 2003 concerning advances in
enantioselective copper catalysed 1, 4-addition of organometallic reagents to α, β …

The copper-catalyzed asymmetric conjugate addition of Grignard reagents to trisubstituted
cyclic enones affords enantioenriched all-carbon quaternary centers with up to 96% ee. The …

The conjugate addition of carbon nucleophiles to acceptor activated olefins is one of the
most important reactions for carbon-carbon bond formation. With optically active metal …

In this Account, recent advances in catalytic asymmetric conjugate addition of Grignard
reagents are discussed. Synthetic methodology to perform highly enantioselective Cu …

A new enabling technology for the pum** of organometallic reagents such as n-
butyllithium, Grignard reagents, and DIBAL-H is reported, which utilises a newly developed …

The direct introduction of sp3 carbon fragments at the β position of α, β-unsaturated
aldehydes is greatly complicated by competing 1, 2-addition manifolds. Previous catalytic …