Mechanochemistry: a force of synthesis
The past decade has seen a reawakening of solid-state approaches to chemical synthesis,
driven by the search for new, cleaner synthetic methodologies. Mechanochemistry, ie …
driven by the search for new, cleaner synthetic methodologies. Mechanochemistry, ie …
Mechanochemistry: opportunities for new and cleaner synthesis
The aim of this critical review is to provide a broad but digestible overview of
mechanochemical synthesis, ie reactions conducted by grinding solid reactants together …
mechanochemical synthesis, ie reactions conducted by grinding solid reactants together …
Mechanochemistry as an emerging tool for molecular synthesis: what can it offer?
Mechanochemistry is becoming more widespread as a technique for molecular synthesis
with new mechanochemical reactions being discovered at increasing frequency. Whilst …
with new mechanochemical reactions being discovered at increasing frequency. Whilst …
Superior toughness and fast self‐healing at room temperature engineered by transparent elastomers
The most important properties of self‐healing polymers are efficient recovery at room
temperature and prolonged durability. However, these two characteristics are contradictory …
temperature and prolonged durability. However, these two characteristics are contradictory …
Mechanochemistry: new tools to navigate the uncharted territory of “impossible” reactions
F Cuccu, L De Luca, F Delogu, E Colacino… - …, 2022 - Wiley Online Library
Mechanochemical transformations have made chemists enter unknown territories, forcing a
different chemistry perspective. While questioning or revisiting familiar concepts belonging …
different chemistry perspective. While questioning or revisiting familiar concepts belonging …
Polymer engineering based on reversible covalent chemistry: A promising innovative pathway towards new materials and new functionalities
ZP Zhang, MZ Rong, MQ Zhang - Progress in Polymer Science, 2018 - Elsevier
Reversible covalent polymers are able to change their bond arrangement and structure via
reversible reaction triggered by external stimuli including heating, light and pH, while …
reversible reaction triggered by external stimuli including heating, light and pH, while …
Altering product selectivity by mechanochemistry
Mechanochemical activation achieved by grinding, shearing, pulling, or milling opens
unique opportunities in synthetic organic chemistry. Common features are that …
unique opportunities in synthetic organic chemistry. Common features are that …
Mechanochemical organic synthesis
GW Wang - Chemical Society Reviews, 2013 - pubs.rsc.org
Recently, mechanical milling using a mixer mill or planetary mill has been fruitfully utilized in
organic synthesis under solvent-free conditions. This review article provides a …
organic synthesis under solvent-free conditions. This review article provides a …
Catalyst-free room-temperature self-healing elastomers based on aromatic disulfide metathesis
A Rekondo, R Martin, AR de Luzuriaga… - Materials …, 2014 - pubs.rsc.org
Aromatic disulfide metathesis has been reported as one of the very few dynamic covalent
chemistries undergone at room-temperature. Here, bis (4-aminophenyl) disulfide is …
chemistries undergone at room-temperature. Here, bis (4-aminophenyl) disulfide is …
Neighboring group participation and internal catalysis effects on exchangeable covalent bonds: application to the thriving field of vitrimer chemistry
F Cuminet, S Caillol, É Dantras, E Leclerc… - …, 2021 - ACS Publications
Vitrimers constitute a fascinating class of polymer materials that make the link between the
historically opposed 3D networks (thermosets) and linear polymers (thermoplastics). Their …
historically opposed 3D networks (thermosets) and linear polymers (thermoplastics). Their …