Mechanochemistry: a force of synthesis

JL Do, T Friščić - ACS central science, 2017 - ACS Publications
The past decade has seen a reawakening of solid-state approaches to chemical synthesis,
driven by the search for new, cleaner synthetic methodologies. Mechanochemistry, ie …

Mechanochemistry: opportunities for new and cleaner synthesis

SL James, CJ Adams, C Bolm, D Braga… - Chemical Society …, 2012 - pubs.rsc.org
The aim of this critical review is to provide a broad but digestible overview of
mechanochemical synthesis, ie reactions conducted by grinding solid reactants together …

Mechanochemistry as an emerging tool for molecular synthesis: what can it offer?

JL Howard, Q Cao, DL Browne - Chemical science, 2018 - pubs.rsc.org
Mechanochemistry is becoming more widespread as a technique for molecular synthesis
with new mechanochemical reactions being discovered at increasing frequency. Whilst …

Superior toughness and fast self‐healing at room temperature engineered by transparent elastomers

SM Kim, H Jeon, SH Shin, SA Park, J Jegal… - Advanced …, 2018 - Wiley Online Library
The most important properties of self‐healing polymers are efficient recovery at room
temperature and prolonged durability. However, these two characteristics are contradictory …

Mechanochemistry: new tools to navigate the uncharted territory of “impossible” reactions

F Cuccu, L De Luca, F Delogu, E Colacino… - …, 2022 - Wiley Online Library
Mechanochemical transformations have made chemists enter unknown territories, forcing a
different chemistry perspective. While questioning or revisiting familiar concepts belonging …

Polymer engineering based on reversible covalent chemistry: A promising innovative pathway towards new materials and new functionalities

ZP Zhang, MZ Rong, MQ Zhang - Progress in Polymer Science, 2018 - Elsevier
Reversible covalent polymers are able to change their bond arrangement and structure via
reversible reaction triggered by external stimuli including heating, light and pH, while …

Altering product selectivity by mechanochemistry

JG Hernández, C Bolm - The Journal of organic chemistry, 2017 - ACS Publications
Mechanochemical activation achieved by grinding, shearing, pulling, or milling opens
unique opportunities in synthetic organic chemistry. Common features are that …

Mechanochemical organic synthesis

GW Wang - Chemical Society Reviews, 2013 - pubs.rsc.org
Recently, mechanical milling using a mixer mill or planetary mill has been fruitfully utilized in
organic synthesis under solvent-free conditions. This review article provides a …

Catalyst-free room-temperature self-healing elastomers based on aromatic disulfide metathesis

A Rekondo, R Martin, AR de Luzuriaga… - Materials …, 2014 - pubs.rsc.org
Aromatic disulfide metathesis has been reported as one of the very few dynamic covalent
chemistries undergone at room-temperature. Here, bis (4-aminophenyl) disulfide is …

Neighboring group participation and internal catalysis effects on exchangeable covalent bonds: application to the thriving field of vitrimer chemistry

F Cuminet, S Caillol, É Dantras, E Leclerc… - …, 2021 - ACS Publications
Vitrimers constitute a fascinating class of polymer materials that make the link between the
historically opposed 3D networks (thermosets) and linear polymers (thermoplastics). Their …