Dynamic covalent synthesis
Dynamic covalent synthesis aims to precisely control the assembly of simple building blocks
linked by reversible covalent bonds to generate a single, structurally complex product. In …
linked by reversible covalent bonds to generate a single, structurally complex product. In …
Mutualistic Synthesis from Orthogonal Dynamic Covalent Reactions
Y Lyu, Y Hu, J Yang, X Wang, J Li - Angewandte Chemie …, 2024 - Wiley Online Library
Mutualisms are interactions that benefit all species involved. It has been widely investigated
in neighbouring subjects, such as biology, ecology, sociology, and economics. However …
in neighbouring subjects, such as biology, ecology, sociology, and economics. However …
Sulfate-induced large amplitude conformational change in a Solomon link
A doubly-interlocked [2] catenane–or Solomon link–undergoes a complex conformational
change upon addition of sulfate in methanol. This transformation generates a single pocket …
change upon addition of sulfate in methanol. This transformation generates a single pocket …
Thermally-induced atropisomerism promotes metal-organic cage construction
J Liang, S Lu, Y Yang, YJ Shen, JK Bai, X Sun… - Nature …, 2023 - nature.com
Molecular folding regulation with environmental stimuli is critical in living and artificial
molecular machine systems. Herein, we described a macrocycle, cyclo [4](1, 3-(4, 6 …
molecular machine systems. Herein, we described a macrocycle, cyclo [4](1, 3-(4, 6 …
Triply Adaptive Libraries of Dynamic Covalent Macrocycles: Switching between Sorted and Unsorted States
Z Yang, F Esteve, C Antheaume… - Journal of the American …, 2024 - ACS Publications
Dynamic noncovalent and covalent chemistries have enabled the constitutional modulation
of chemical entities within chemical dynamic systems. The switching between order and …
of chemical entities within chemical dynamic systems. The switching between order and …
Simultaneous Formation of a Foldamer and a Self-Replicator by Out-of-Equilibrium Dynamic Covalent Chemistry
Systems chemistry has emerged as a useful paradigm to access structures and phenomena
typically exhibited by living systems, including complex molecular systems such as self …
typically exhibited by living systems, including complex molecular systems such as self …
Redox-Regulated and Guest-Driven Transformations of Aromatic Oligoamide Foldamers in Advanced Structures
L Yu, D Li, C Ma, B Kauffmann, S Liao… - Journal of the American …, 2024 - ACS Publications
In this study, we demonstrate that an aromatic oligoamide sequence assembles into a
trimeric helix-turn-helix architecture with a disulfide linkage, and upon cleavage of this …
trimeric helix-turn-helix architecture with a disulfide linkage, and upon cleavage of this …
Dual, Photo‐Responsive and Redox‐Active Supramolecular Foldamers
AR Davis, JO Dismorr, L Male… - … –A European Journal, 2024 - Wiley Online Library
We report on dual, light‐responsive and redox‐active foldamers that demonstrate reversible
and robust stimuli‐induced behaviour. Herein, UV/Vis, 1H NMR and circular dichroism (CD) …
and robust stimuli‐induced behaviour. Herein, UV/Vis, 1H NMR and circular dichroism (CD) …
Engineering chiral arms in folded molecular motors
Y **a, A Hao, P **ng - Science China Chemistry, 2025 - Springer
Controllable molecular motion in chiral folded structures could realize switchable properties
that facilitate the rational fabrication of smart chiroptical devices. In this work, we illustrate the …
that facilitate the rational fabrication of smart chiroptical devices. In this work, we illustrate the …
Expanding the scope of phosphorylase-mediated dynamic combinatorial chemistry
S Reiner - 2023 - orbit.dtu.dk
Carbohydrates are some of the most important biopolymers, along with proteins and
polynucleotides. In nature, glycans are used for energy storage, as structural fibers, and for …
polynucleotides. In nature, glycans are used for energy storage, as structural fibers, and for …