Dynamic covalent synthesis

FBL Cougnon, AR Stefankiewicz, S Ulrich - Chemical Science, 2024 - pubs.rsc.org
Dynamic covalent synthesis aims to precisely control the assembly of simple building blocks
linked by reversible covalent bonds to generate a single, structurally complex product. In …

Mutualistic Synthesis from Orthogonal Dynamic Covalent Reactions

Y Lyu, Y Hu, J Yang, X Wang, J Li - Angewandte Chemie …, 2024 - Wiley Online Library
Mutualisms are interactions that benefit all species involved. It has been widely investigated
in neighbouring subjects, such as biology, ecology, sociology, and economics. However …

Sulfate-induced large amplitude conformational change in a Solomon link

CD Do, D Pál, A Belyaev, M Pupier, A Kiesilä… - Chemical …, 2023 - pubs.rsc.org
A doubly-interlocked [2] catenane–or Solomon link–undergoes a complex conformational
change upon addition of sulfate in methanol. This transformation generates a single pocket …

Thermally-induced atropisomerism promotes metal-organic cage construction

J Liang, S Lu, Y Yang, YJ Shen, JK Bai, X Sun… - Nature …, 2023 - nature.com
Molecular folding regulation with environmental stimuli is critical in living and artificial
molecular machine systems. Herein, we described a macrocycle, cyclo [4](1, 3-(4, 6 …

Triply Adaptive Libraries of Dynamic Covalent Macrocycles: Switching between Sorted and Unsorted States

Z Yang, F Esteve, C Antheaume… - Journal of the American …, 2024 - ACS Publications
Dynamic noncovalent and covalent chemistries have enabled the constitutional modulation
of chemical entities within chemical dynamic systems. The switching between order and …

Simultaneous Formation of a Foldamer and a Self-Replicator by Out-of-Equilibrium Dynamic Covalent Chemistry

A Sood, PK Mandal, J Ottelé, J Wu… - Journal of the …, 2024 - ACS Publications
Systems chemistry has emerged as a useful paradigm to access structures and phenomena
typically exhibited by living systems, including complex molecular systems such as self …

Redox-Regulated and Guest-Driven Transformations of Aromatic Oligoamide Foldamers in Advanced Structures

L Yu, D Li, C Ma, B Kauffmann, S Liao… - Journal of the American …, 2024 - ACS Publications
In this study, we demonstrate that an aromatic oligoamide sequence assembles into a
trimeric helix-turn-helix architecture with a disulfide linkage, and upon cleavage of this …

Dual, Photo‐Responsive and Redox‐Active Supramolecular Foldamers

AR Davis, JO Dismorr, L Male… - … –A European Journal, 2024 - Wiley Online Library
We report on dual, light‐responsive and redox‐active foldamers that demonstrate reversible
and robust stimuli‐induced behaviour. Herein, UV/Vis, 1H NMR and circular dichroism (CD) …

Engineering chiral arms in folded molecular motors

Y **a, A Hao, P **ng - Science China Chemistry, 2025 - Springer
Controllable molecular motion in chiral folded structures could realize switchable properties
that facilitate the rational fabrication of smart chiroptical devices. In this work, we illustrate the …

Expanding the scope of phosphorylase-mediated dynamic combinatorial chemistry

S Reiner - 2023 - orbit.dtu.dk
Carbohydrates are some of the most important biopolymers, along with proteins and
polynucleotides. In nature, glycans are used for energy storage, as structural fibers, and for …