Sulfur fluoride exchange
Click chemistry is a conceptual strategy to rapidly synthesize and discover functional
molecules. Sulfur fluoride exchange (SuFEx) is a click reaction that has revolutionized …
molecules. Sulfur fluoride exchange (SuFEx) is a click reaction that has revolutionized …
Linkage chemistry of S (VI) fluorides
D Zeng, WP Deng, X Jiang - Chemistry–A European Journal, 2023 - Wiley Online Library
Sulfur (VI)‐fluoride exchange linkage as a next generation of click chemistry was introduced
by Sharpless and coworkers in 2014. Distinguished from CuAAC, the SuFEx reaction …
by Sharpless and coworkers in 2014. Distinguished from CuAAC, the SuFEx reaction …
Enantioselective sulfur (VI) fluoride exchange reaction of iminosulfur oxydifluorides
Linkage chemistry and functional molecules derived from the stereogenic sulfur (VI) centre
have important applications in organic synthesis, bioconjugation, drug discovery …
have important applications in organic synthesis, bioconjugation, drug discovery …
Robust covalent aptamer strategy enables sensitive detection and enhanced inhibition of SARS-CoV-2 proteins
Aptamer-based detection and therapy have made substantial progress with cost control and
easy modification. However, the conformation lability of an aptamer typically causes the …
easy modification. However, the conformation lability of an aptamer typically causes the …
Fluorosulfonylvinylation of Unactivated C(sp3)–H via Electron Donor–Acceptor Photoactivation
X Zhao, D Chen, S Zhu, J Luo, S Liao, B Zheng… - Organic …, 2023 - ACS Publications
An electron donor–acceptor (EDA) complex photoactivation strategy for radical
fluorosulfonylation is disclosed for the first time. Simply upon blue light irradiation, the FSO2 …
fluorosulfonylation is disclosed for the first time. Simply upon blue light irradiation, the FSO2 …
Mechanism‐Guided Design of Chain‐Growth Click Polymerization Based on a Thiol‐Michael Reaction
The development of chain‐growth click polymerization is challenging yet desirable in
modern polymer chemistry. In this work, we reported a novel chain‐growth click …
modern polymer chemistry. In this work, we reported a novel chain‐growth click …
C (sp 3)–H fluorosulfonylvinylation/aza-Michael addition approach to FSO 2-functionalized tetrahydropyridines
S Shi, X Zhao, D Chen, J Luo, S Liao… - Organic Chemistry …, 2023 - pubs.rsc.org
A novel cascade approach is presented for the synthesis of FSO2-functionalized
tetrahydropyridines from propargyl alcohols, FSO2Cl, and anilines. This strategy …
tetrahydropyridines from propargyl alcohols, FSO2Cl, and anilines. This strategy …
Synthesis of Degradable Polysulfamides via Sulfur (VI) Fluoride Exchange Click Polymerization of AB-Type Monomers
JW Wu, RW Kulow, MKJ Redding, AJ Fine… - ACS Polymers …, 2023 - ACS Publications
Polysulfamides are the− SO2–analogues of polyureas and form an intriguing family of
polymers containing hydrogen-bond donor and acceptor groups. However, unlike …
polymers containing hydrogen-bond donor and acceptor groups. However, unlike …
Machine learning-accelerated discovery of heat-resistant polysulfates for electrostatic energy storage
The development of heat-resistant dielectric polymers that withstand intense electric fields at
high temperatures is critical for electrification. Balancing thermal stability and electrical …
high temperatures is critical for electrification. Balancing thermal stability and electrical …
Sulfur-phenolate exchange as a fluorine-free approach to S (VI) exchange chemistry on sulfonyl moieties
SuFEx chemistry has recently evolved as next-generation click chemistry. However, in most
SuFEx syntheses, additional reagents/catalysts and carefully controlled conditions are still …
SuFEx syntheses, additional reagents/catalysts and carefully controlled conditions are still …