Metal–organic cages (MOCs) are discrete, supramolecular entities that consist of metal
nodes and organic linkers, which can offer solution processability and high porosity …

In this review, a comprehensive summary of supramolecular transformations within discrete
coordination-driven supramolecular architectures, including helices, metallacycles …

In recent past years, investigation of hierarchical self-assembly for constructing artificial
functional materials has attracted considerable attention. Discrete metallacycles based on …

Post‐synthetic modification (PSM) is an effective approach for the tailored functionalization
of metal‐organic architectures, but its generalizability remains challenging. Herein we report …

Self-assembly is a potent synthetic tool that allowed chemists to design numerous complex
structures, supramolecules of various shapes from relatively simple starting materials. Metal …

Postassembly modification strategy has been successfully employed in the construction of
discrete metallosupramolecular assemblies. However, the most known reports have been …

A growing variety of covalent reactions have been employed to achieve the post-assembly
modification (PAM) of self-assembled metallosupramolecular complexes. Covalent PAM …

The anthracene panels of two tetrahedral MII4L6 cages, where MII= CoII or FeII, were found
to react with photogenerated singlet oxygen (1O2) in a hetero‐Diels–Alder reaction. ESI‐MS …

In dynamic covalent synthesis, kinetic traps are perceived as disadvantageous, hindering
the system from reaching its thermodynamic equilibrium. Here we present the near …

Supramolecular polymers have received considerable attention during the last few decades
due to their scientific value in polymer chemistry and profound implications for future …