Optimizing catalyst and reaction conditions in gold (I) catalysis–ligand development
This review considers phosphine and N-heterocyclic carbene complexes of gold (I) that are
used as (pre) catalysts for a range of reactions in organic synthesis. These are divided …
used as (pre) catalysts for a range of reactions in organic synthesis. These are divided …
Water in N-heterocyclic carbene-assisted catalysis
Water is one of the most abundant molecules on earth. It is inexpensive, especially when
compared to organic solvents, nonflammable, and nontoxic, it has a large heat capacity, and …
compared to organic solvents, nonflammable, and nontoxic, it has a large heat capacity, and …
Hydration reactions catalyzed by transition metal–NHC (NHC= N-heterocyclic carbene) complexes
P Gao, M Szostak - Coordination Chemistry Reviews, 2023 - Elsevier
The catalytic addition of water to unsaturated C–C or C–N π bonds represent one of the
most important and environmentally sustainable methods to form C–O bonds for the …
most important and environmentally sustainable methods to form C–O bonds for the …
Supported Au Nanoparticles with N-Heterocyclic Carbene Ligands as Active and Stable Heterogeneous Catalysts for Lactonization
Attachment of N-heterocyclic carbenes (NHCs) on the surface of metal nanoparticle (NP)
catalysts permits fine-tuning of catalytic activity and product selectivity. Yet, NHC-coated Au …
catalysts permits fine-tuning of catalytic activity and product selectivity. Yet, NHC-coated Au …
Solvent-, silver-, and acid-free NHC-Au-X catalyzed hydration of alkynes. The pivotal role of the counterion
NHC-Au-X (NHC= 1, 3-bis (2, 6-diisopropylphenyl) imidazol-2-ylidene, X–= BArF–, BF4–,
SbF6–, OTf–, NTf2–, ClO4–, OTs–, TFA–) catalysts were tested in the hydration of alkynes. A …
SbF6–, OTf–, NTf2–, ClO4–, OTs–, TFA–) catalysts were tested in the hydration of alkynes. A …
Generation of gold carbenes in water: efficient intermolecular trap** of the α-oxo gold carbenoids by indoles and anilines
L Li, C Shu, B Zhou, YF Yu, XY **ao, LW Ye - Chemical Science, 2014 - pubs.rsc.org
The efficient intermolecular reaction of gold carbene intermediates, generated via gold-
catalyzed alkyne oxidation, with indoles and anilines has been realized in aqueous media …
catalyzed alkyne oxidation, with indoles and anilines has been realized in aqueous media …
Characterization of hydrophilic gold (I) N-heterocyclic carbene (NHC) complexes as potent TrxR inhibitors using biochemical and mass spectrometric approaches
O Karaca, V Scalcon, SM Meier-Menches… - Inorganic …, 2017 - ACS Publications
We report here on the synthesis of a series of mono-and dinuclear gold (I) complexes
exhibiting sulfonated bis (NHC) ligands and novel hydroxylated mono (NHC) Au (I) …
exhibiting sulfonated bis (NHC) ligands and novel hydroxylated mono (NHC) Au (I) …
Silver-Free Catalysis with Gold (I) Chloride Complexes
Gold (I) chloride complexes are stable, widespread precatalysts that generally require
activation by halide abstraction to display useful catalytic activity. Chloride scavenging is …
activation by halide abstraction to display useful catalytic activity. Chloride scavenging is …
Hydration of alkynes at room temperature catalyzed by gold (I) isocyanide compounds
Y Xu, X Hu, J Shao, G Yang, Y Wu, Z Zhang - Green Chemistry, 2015 - pubs.rsc.org
An effective method using gold (I) isocyanide complexes as catalysts for the transformation
of various alkynes to the corresponding ketones is successfully developed. The hydration …
of various alkynes to the corresponding ketones is successfully developed. The hydration …
Galactopyranoside-Substituted N-Heterocyclic Carbene Gold(I) Complexes: Synthesis, Stability, and Catalytic Applications to Alkyne Hydration
AW Hobsteter, MA Badajoz, MJ Lo Fiego… - ACS …, 2022 - ACS Publications
A series of novel gold (I) complexes bearing galactopyranoside-based N-heterocyclic
carbene ligands have been synthesized via transmetalation of the corresponding Ag (I) …
carbene ligands have been synthesized via transmetalation of the corresponding Ag (I) …