Solvent-assisted self-assembly of block copolymer thin films

P Pula, A Leniart, PW Majewski - Soft Matter, 2022 - pubs.rsc.org
Solvent-assisted block copolymer self-assembly is a compelling method for processing and
advancing practical applications of these materials due to the exceptional level of the control …

Directed block copolymer thin film self-assembly: emerging trends in nanopattern fabrication

M Luo, TH Epps III - Macromolecules, 2013 - ACS Publications
Block copolymers have garnered significant attention in the past few decades due to their
ability to self-assemble into nanoscale structures (∼ 10–100 nm), making them ideal for …

Exploiting molecular weight distribution shape to tune domain spacing in block copolymer thin films

DT Gentekos, J Jia, ES Tirado, KP Barteau… - Journal of the …, 2018 - ACS Publications
We report a method for tuning the domain spacing (D sp) of self-assembled block copolymer
thin films of poly (styrene-block-methyl methacrylate)(PS-b-PMMA) over a large range of …

Dispersing nanoparticles in a polymer film via solvent evaporation

S Cheng, GS Grest - ACS Macro Letters, 2016 - ACS Publications
Large-scale molecular dynamics simulations are used to study the dispersion of
nanoparticles (NPs) in a polymer film during solvent evaporation. As the solvent evaporates …

Block copolymer thin films: Characterizing nanostructure evolution with in situ X-ray and neutron scattering

CK Shelton, TH Epps III - Polymer, 2016 - Elsevier
Block copolymer (BCP) thin films have attracted significant attention as lithographic
templates, separation membranes, and organic photovoltaic active layers for emerging …

Sequence-Defined Multiblock Copolymer Nanoengineered Particles from Polymerization-Induced Self-Assembly (PISA): Synthesis and Film Formation

SW Thompson, TR Guimarães, PB Zetterlund - Macromolecules, 2023 - ACS Publications
Multiblock copolymers synthesized via reversible addition–fragmentation transfer (RAFT)
emulsion polymerization offer a pathway to creating new nanoengineered materials …

Swift Nanopattern Formation of PS-b-PMMA and PS-b-PDMS Block Copolymer Films Using a Microwave Assisted Technique

D Borah, R Senthamaraikannan, S Rasappa… - Acs Nano, 2013 - ACS Publications
Microphase separation of block copolymer (BCPs) thin films has high potential as a surface
patterning technique. However, the process times (during thermal or solvent anneal) can be …

Responsive blends of block copolymers stabilize the hexagonally perforated lamellae morphology

SR Nowak, N Tiwale, GS Doerk, CY Nam, CT Black… - Soft Matter, 2023 - pubs.rsc.org
Blends of block copolymers can form phases and exhibit features distinct from the
constituent materials. We study thin film blends of cylinder-forming and lamellar-forming …

Ordering dynamics in symmetric PS-b-PMMA diblock copolymer thin films during rapid thermal processing

M Perego, FF Lupi, M Ceresoli, TJ Giammaria… - Journal of Materials …, 2014 - pubs.rsc.org
The pattern coarsening dynamics in symmetric polystyrene-b-polymethylmethacrylate (PS-b-
PMMA) block copolymer thin films under conventional thermal treatments is extremely slow …

On-Demand Selection of the Latent Domain Orientation in Spray-Deposited Block Copolymer Thin Films

S Cetindag, B Bellini, R Li, EHR Tsai, D Nykypanchuk… - ACS …, 2025 - ACS Publications
With their ability to self-assemble spontaneously into well-defined nanoscale morphologies,
block copolymer (BCP) thin films are a versatile platform to fabricate functional …