A review of state of the art in phosphine ligated gold clusters and application in catalysis
Atomically precise gold clusters are highly desirable due to their well‐defined structure
which allows the study of structure–property relationships. In addition, they have potential in …
which allows the study of structure–property relationships. In addition, they have potential in …
Coinage metal clusters: From superatom chemistry to genetic materials
B Yin, Z Luo - Coordination Chemistry Reviews, 2021 - Elsevier
Building metal materials with well-defined components and the monomer-genetic property is
one of the foremost challenges in chemistry and materials science. In recent years, metal …
one of the foremost challenges in chemistry and materials science. In recent years, metal …
Suppression of kernel vibrations by layer-by-layer ligand engineering boosts photoluminescence efficiency of gold nanoclusters
The restriction of structural vibration has assumed great importance in attaining bright
emission of luminescent metal nanoclusters (NCs), where tremendous efforts are devoted to …
emission of luminescent metal nanoclusters (NCs), where tremendous efforts are devoted to …
Mechanistic Study of the Hydride Migration-Induced Reversible Isomerization in Au22(SR)15H Isomers
Q Li, Y Tan, B Huang, S Yang, J Chai… - Journal of the …, 2023 - ACS Publications
Unraveling the evolution mechanism of metal nanoclusters is of great importance in
understanding the formation and evolution of metallic condensed matters. In this work, the …
understanding the formation and evolution of metallic condensed matters. In this work, the …
Crystal Structure of Faradaurate-279: Au279(SPh-tBu)84 Plasmonic Nanocrystal Molecules
We report the discovery of an unprecedentedly large, 2.2 nm diameter, thiolate protected
gold nanocrystal characterized by single crystal X-ray crystallography (sc-XRD), Au279 (SPh …
gold nanocrystal characterized by single crystal X-ray crystallography (sc-XRD), Au279 (SPh …
Cd atom goes into the interior of cluster induced by directional consecutive assembly of tetrahedral units on an icosahedron kernel
Y Tan, Y Lv, L Xu, Q Li, J Chai, S Yang… - Journal of the …, 2023 - ACS Publications
“Core sliding” in metal nanoclusters drives the reconstruction of external structural units and
provides an ideal platform for map** their precise transformation mechanism and …
provides an ideal platform for map** their precise transformation mechanism and …
Tailoring the Structure of 58-Electron Gold Nanoclusters: Au103S2(S-Nap)41 and Its Implications
We report the synthesis and crystal structure determination of a gold nanocluster with 103
gold atoms protected by 2 sulfidos and 41 thiolates (ie, 2-naphthalenethiolates, S-Nap) …
gold atoms protected by 2 sulfidos and 41 thiolates (ie, 2-naphthalenethiolates, S-Nap) …
Toward controlled syntheses of diphosphine-protected homochiral gold nanoclusters through precursor engineering
WD Si, YZ Li, SS Zhang, S Wang, L Feng, ZY Gao… - ACS …, 2021 - ACS Publications
Controllable syntheses of Au nanoclusters (NCs) with different nuclearities are of great
significance due to the kernel-dependent physicochemical properties. Herein, two pairs of …
significance due to the kernel-dependent physicochemical properties. Herein, two pairs of …
Growth-rule-guided structural exploration of thiolate-protected gold nanoclusters
Y Pei, P Wang, Z Ma, L **ong - Accounts of Chemical Research, 2018 - ACS Publications
Conspectus Understanding the structure and structure–property relationship of atomic and
ligated clusters is one of the central research tasks in the field of cluster research. In …
ligated clusters is one of the central research tasks in the field of cluster research. In …
De novo design of Au36(SR)24 nanoclusters
X Liu, WW Xu, X Huang, E Wang, X Cai, Y Zhao… - Nature …, 2020 - nature.com
The discovery of atomically precise nanoclusters is generally unpredictable, and the rational
synthesis of nanoclusters guided by the theoretical design is still in its infancy. Here we …
synthesis of nanoclusters guided by the theoretical design is still in its infancy. Here we …