Understanding Lattice Oxygen Redox Behavior in Lithium‐Rich Manganese‐Based Layered Oxides for Lithium‐Ion and Lithium‐Metal Batteries from Reaction …

C Shen, L Hu, Q Duan, X Liu, S Huang… - Advanced Energy …, 2023 - Wiley Online Library
Lithium‐rich manganese‐based layered oxides (LMLOs) are considered to be one type of
the most promising materials for next‐generation cathodes of lithium batteries due to their …

Electrochemical activation, sintering, and reconstruction in energy‐storage technologies: origin, development, and prospects

D Zhang, J Lu, C Pei, S Ni - Advanced Energy Materials, 2022 - Wiley Online Library
Although there has been significant progress in designing electrode materials and exploring
the electrochemical reaction mechanisms in battery systems, the morphological, structural …

Oxygen‐Vacancy‐Assisted Dual Functional Surface Coatings Suppressing Irreversible Phase Transition of Li‐Rich Layered Oxide Cathodes

Q Jiang, X Li, Y Hao, J Zuo, R Duan, J Li… - Advanced Functional …, 2025 - Wiley Online Library
Both lattice oxygen release and the migration of transition metal (TM) ions challenge the
cyclability of Li‐rich Mn‐based layered oxide (LMO) cathodes by inducing irreversible phase …

Coupling Antisite Defect and Lattice Tensile Stimulates Facile Isotropic Li‐Ion Diffusion

J Luo, J Zhang, Z Guo, Z Liu, C Wang… - Advanced …, 2024 - Wiley Online Library
Despite widely used as a commercial cathode, the anisotropic 1D channel hop** of
lithium ions along the [010] direction in LiFePO4 prevents its application in fast charging …

Voltage decay of Li‐rich layered oxides: mechanism, modification strategies, and perspectives

L Zeng, H Liang, B Qiu, Z Shi, S Cheng… - Advanced Functional …, 2023 - Wiley Online Library
Li‐rich layered oxides (LLOs) have been considered as the most promising cathode
materials for achieving high energy density Li‐ion batteries. However, they suffer from …

Al/Ti synergistic do** enhanced cycle stability of Li‐rich layered oxides

E Wang, D **ao, T Wu, X Liu, Y Zhou… - Advanced Functional …, 2022 - Wiley Online Library
Li‐rich layered oxides (LLOs) suffer from rapid voltage decay and capacity fading, greatly
hindering their applications as high‐energy cathode materials for Li‐ion batteries (LIBs) …

High-voltage LiCoO2 cathodes for high-energy-density lithium-ion battery

JC Zhang, ZD Liu, CH Zeng, JW Luo, YD Deng, XY Cui… - Rare Metals, 2022 - Springer
As the earliest commercial cathode material for lithium-ion batteries, lithium cobalt oxide
(LiCoO2) shows various advantages, including high theoretical capacity, excellent rate …

From oxygen redox to sulfur redox: a paradigm for Li-rich layered cathodes

JC Li, J Tang, J Tian, C Cheng, Y Liao… - Journal of the …, 2024 - ACS Publications
The utilization of anionic redox chemistry provides an opportunity to further improve the
energy density of Li-ion batteries, particularly for Li-rich layered oxides. However, oxygen …

Recent advances in lithium-rich manganese-based cathodes for high energy density lithium-ion batteries

H Chen, C Sun - Chemical Communications, 2023 - pubs.rsc.org
The development of society challenges the limit of lithium-ion batteries (LIBs) in terms of
energy density and safety. Lithium-rich manganese oxide (LRMO) is regarded as one of the …

Single-crystal Li-rich layered cathodes with suppressed voltage decay by double-layer interface engineering

W Zeng, F Liu, J Yang, B Zhang, F Cao, W Tian… - Energy Storage …, 2023 - Elsevier
Despite lithium-rich layered oxides (LLO) are promising candidates for the next-generation
cathode materials, the rapid voltage and capacity decay, caused by structural degradation …