Roles of the hydrogen atoms attached to the metal center of transition metal polyhydride
complexes, LnMHx (x≥ 3), are analyzed for about forty types of organic reactions catalyzed …

The preparation, structure, dynamic behavior in solution, and reactivity of polyhydride
complexes of platinum group metals, described during the last three decades, are …

In the presence of KOBut, N-heterocyclic carbene-supported half-sandwich complex [Cp
(IPr) Ru (pyr) 2][PF6](3)(IPr= 1, 3-bis (2, 6-diisopropylphenyl) imidazol-2-ylidene) catalyzes …

The computation of metal–silyl interaction energies indicates the existence of situations in
which the silyl group behaves as a Z‐type ligand according to the Green method of covalent …

The NHC (NHC= N-heterocyclic carbene) complex Cp*(IPr) RuH3 catalyzes
hydrodefluorination of aromatic fluorides at 70° C with isopropyl alcohol as the reducing …

An entry to mixed phosphine–osmium–NHC polyhydride complexes is described, starting
from the five-coordinate hydrido–alkylidyne compounds [OsHCl ( CPh)(IPr)(PR3)] OTf (IPr …

NHC-supported trihydrides Cp (NHC) RuH3 show excellent catalytic activity in the H/D
exchange of pyridine and some other N-heterocycles under mild conditions and low catalyst …

A series of half‐sandwich phosphine‐and NHC‐supported complexes were screened in
catalytic transfer hydrogenation of nitriles, N‐heterocycles, olefins, and carbonyls by using …

A series of cationic half-sandwich cyclopentadienyl–ruthenium (II)–pyridylamine
complexes,[(η5-C5H5) Ru (κ2-L)(PPh3)]+(L= Namine-substituted pyridylamine ligands)([Ru] …

Reactions of carbene complex [Cp (IPr) Ru (pyr) 2][BF4](6, IPr= 1, 3-bis (2, 6-
diisopropylphenyl) imidazol-2-ylidene) with excess acetonitrile and LiCl in THF afford …