Synthetic strategies towards chiral coordination polymers
HM Tay, N Kyratzis, S Thoonen, SA Boer… - Coordination Chemistry …, 2021 - Elsevier
Chiral coordination polymers and porous chiral MOFs have great potential as agents for
enantioselective separations, sensing, and catalysis due to their well-structured internal …
enantioselective separations, sensing, and catalysis due to their well-structured internal …
Chemistry and applications of s-block metal–organic frameworks
Metal–organic frameworks (MOFs) are crystalline porous materials with a broad range of
practical applications. A plethora of MOFs based on a variety of metal ions including s-, p-, d …
practical applications. A plethora of MOFs based on a variety of metal ions including s-, p-, d …
An Octacarboxylate-Linked Sodium Metal–Organic Framework with High Porosity
J Miao, W Graham, J Liu, EC Hill, LL Ma… - Journal of the …, 2023 - ACS Publications
Alkali metal-based metal–organic frameworks (MOFs) with permanent porosity are scarce
because of their high tendency to coordinate with solvents such as water. However, these …
because of their high tendency to coordinate with solvents such as water. However, these …
A potassium metal-organic framework based on perylene-3, 4, 9, 10-tetracarboxylate as sensing layer for humidity actuators
We have synthesized a novel three-dimensional metal-organic-framework (MOF) based on
the perylene-3, 4, 9, 10-tetracarboxylate linker and potassium as metallic centre. We report …
the perylene-3, 4, 9, 10-tetracarboxylate linker and potassium as metallic centre. We report …
Integration of rigid and flexible organic parts for the construction of a homochiral metal–organic framework with high porosity
ZX Xu, YX Tan, HR Fu, Y Kang, J Zhang - Chemical Communications, 2015 - pubs.rsc.org
Presented is a pair of homochiral metal–organic frameworks built from mixed ligands
integrating rigid and flexible organic parts, and each compound shows high porosity and …
integrating rigid and flexible organic parts, and each compound shows high porosity and …
Supramolecular metal–organic frameworks of s-and f-block metals: impact of 1, 8-naphthalimide functional group
DL Reger, AP Leitner, MD Smith - Crystal Growth & Design, 2016 - ACS Publications
The new ligand 5-(1, 8-naphthalimido) isophthalate (L 135 2–), containing two carboxylate
donor groups and the 1, 8-naphthalimide supramolecular tecton, has been used under …
donor groups and the 1, 8-naphthalimide supramolecular tecton, has been used under …
A 3D MOF showing unprecedented solvent-induced single-crystal-to-single-crystal transformation and excellent CO 2 adsorption selectivity at room temperature
T Qin, J Gong, J Ma, X Wang, Y Wang, Y Xu… - Chemical …, 2014 - pubs.rsc.org
A water stable porous 3D metal–organic framework,[Cu3L2 (μ3-OH) 2 (μ2-H2O)]· 2DMA (1,
mother crystal, H2L= 2, 2′-dinitrobiphenyl-4, 4′-dicarboxylic acid, DMA= N, N …
mother crystal, H2L= 2, 2′-dinitrobiphenyl-4, 4′-dicarboxylic acid, DMA= N, N …
Coordination chemistry of N-picolyl-1, 8-naphthalimides: colourful low molecular weight metallo-gelators and unique chelation behaviours
We have prepared a series of N-picolyl-1, 8-naphthalimide derivatives and explored their
coordination chemistry with d-block metal ions in the solid and solution states, and exploited …
coordination chemistry with d-block metal ions in the solid and solution states, and exploited …
l-Aspartate links for stable sodium metal–organic frameworks
Metal–organic frameworks (MOFs) based purely on sodium are rare, typically due to large
numbers of coordinating solvent ligands. We designed a tetratopic aspartate-based linker …
numbers of coordinating solvent ligands. We designed a tetratopic aspartate-based linker …
Asymmetric induction in homochiral MOFs: from interweaving double helices to single helices
X Wu, HB Zhang, ZX Xu, J Zhang - Chemical Communications, 2015 - pubs.rsc.org
Two three-dimensional (3D) homochiral metal–organic frameworks, integrating double
helical chains based on enantiopure ligands and single helical structures braided by 4, 4 …
helical chains based on enantiopure ligands and single helical structures braided by 4, 4 …