Synthetic strategies towards chiral coordination polymers

HM Tay, N Kyratzis, S Thoonen, SA Boer… - Coordination Chemistry …, 2021 - Elsevier
Chiral coordination polymers and porous chiral MOFs have great potential as agents for
enantioselective separations, sensing, and catalysis due to their well-structured internal …

Chemistry and applications of s-block metal–organic frameworks

MA Alnaqbi, A Alzamly, SH Ahmed, M Bakiro… - Journal of Materials …, 2021 - pubs.rsc.org
Metal–organic frameworks (MOFs) are crystalline porous materials with a broad range of
practical applications. A plethora of MOFs based on a variety of metal ions including s-, p-, d …

An Octacarboxylate-Linked Sodium Metal–Organic Framework with High Porosity

J Miao, W Graham, J Liu, EC Hill, LL Ma… - Journal of the …, 2023 - ACS Publications
Alkali metal-based metal–organic frameworks (MOFs) with permanent porosity are scarce
because of their high tendency to coordinate with solvents such as water. However, these …

A potassium metal-organic framework based on perylene-3, 4, 9, 10-tetracarboxylate as sensing layer for humidity actuators

JM Seco, E San Sebastián, J Cepeda, B Biel… - Scientific Reports, 2018 - nature.com
We have synthesized a novel three-dimensional metal-organic-framework (MOF) based on
the perylene-3, 4, 9, 10-tetracarboxylate linker and potassium as metallic centre. We report …

Integration of rigid and flexible organic parts for the construction of a homochiral metal–organic framework with high porosity

ZX Xu, YX Tan, HR Fu, Y Kang, J Zhang - Chemical Communications, 2015 - pubs.rsc.org
Presented is a pair of homochiral metal–organic frameworks built from mixed ligands
integrating rigid and flexible organic parts, and each compound shows high porosity and …

Supramolecular metal–organic frameworks of s-and f-block metals: impact of 1, 8-naphthalimide functional group

DL Reger, AP Leitner, MD Smith - Crystal Growth & Design, 2016 - ACS Publications
The new ligand 5-(1, 8-naphthalimido) isophthalate (L 135 2–), containing two carboxylate
donor groups and the 1, 8-naphthalimide supramolecular tecton, has been used under …

A 3D MOF showing unprecedented solvent-induced single-crystal-to-single-crystal transformation and excellent CO 2 adsorption selectivity at room temperature

T Qin, J Gong, J Ma, X Wang, Y Wang, Y Xu… - Chemical …, 2014 - pubs.rsc.org
A water stable porous 3D metal–organic framework,[Cu3L2 (μ3-OH) 2 (μ2-H2O)]· 2DMA (1,
mother crystal, H2L= 2, 2′-dinitrobiphenyl-4, 4′-dicarboxylic acid, DMA= N, N …

Coordination chemistry of N-picolyl-1, 8-naphthalimides: colourful low molecular weight metallo-gelators and unique chelation behaviours

JI Lovitt, CS Hawes, AD Lynes, B Haffner… - Inorganic Chemistry …, 2017 - pubs.rsc.org
We have prepared a series of N-picolyl-1, 8-naphthalimide derivatives and explored their
coordination chemistry with d-block metal ions in the solid and solution states, and exploited …

l-Aspartate links for stable sodium metal–organic frameworks

P Siman, CA Trickett, H Furukawa… - Chemical …, 2015 - pubs.rsc.org
Metal–organic frameworks (MOFs) based purely on sodium are rare, typically due to large
numbers of coordinating solvent ligands. We designed a tetratopic aspartate-based linker …

Asymmetric induction in homochiral MOFs: from interweaving double helices to single helices

X Wu, HB Zhang, ZX Xu, J Zhang - Chemical Communications, 2015 - pubs.rsc.org
Two three-dimensional (3D) homochiral metal–organic frameworks, integrating double
helical chains based on enantiopure ligands and single helical structures braided by 4, 4 …