The rise and current status of polaritonic photochemistry and photophysics

R Bhuyan, J Mony, O Kotov, GW Castellanos… - Chemical …, 2023 - ACS Publications
The interaction between molecular electronic transitions and electromagnetic fields can be
enlarged to the point where distinct hybrid light–matter states, polaritons, emerge. The …

Manipulating matter by strong coupling to vacuum fields

FJ Garcia-Vidal, C Ciuti, TW Ebbesen - Science, 2021 - science.org
BACKGROUND One of the most important phenomena in cavity quantum electrodynamics
(cQED) is the so-called strong coupling regime, which appears when the interaction …

Modification of ground-state chemical reactivity via light–matter coherence in infrared cavities

W Ahn, JF Triana, F Recabal, F Herrera, BS Simpkins - Science, 2023 - science.org
Reaction-rate modifications for chemical processes due to strong coupling between reactant
molecular vibrations and the cavity vacuum have been reported; however, no currently …

Chemistry under vibrational strong coupling

K Nagarajan, A Thomas… - Journal of the American …, 2021 - ACS Publications
Over the past decade, the possibility of manipulating chemistry and material properties using
hybrid light–matter states has stimulated considerable interest. Hybrid light–matter states …

Molecular chemistry in cavity strong coupling

K Hirai, JA Hutchison, H Uji-i - Chemical Reviews, 2023 - ACS Publications
The coherent exchange of energy between materials and optical fields leads to strong light–
matter interactions and so-called polaritonic states with intriguing properties, halfway …

Cavity-enhanced energy transport in molecular systems

G Sandik, J Feist, FJ García-Vidal, T Schwartz - Nature Materials, 2024 - nature.com
Molecules are the building blocks of all of nature's functional components, serving as the
machinery that captures, stores and releases energy or converts it into useful work …

Polariton chemistry: controlling molecular dynamics with optical cavities

RF Ribeiro, LA Martínez-Martínez, M Du… - Chemical …, 2018 - pubs.rsc.org
Molecular polaritons are the optical excitations which emerge when molecular transitions
interact strongly with confined electromagnetic fields. Increasing interest in the hybrid …

Strong light–matter interactions: a new direction within chemistry

M Hertzog, M Wang, J Mony, K Börjesson - Chemical Society Reviews, 2019 - pubs.rsc.org
It is possible to modify the chemical and physical properties of molecules, not only through
chemical modifications but also by coupling molecules strongly to light. More intriguingly …

Hybrid light–matter states in a molecular and material science perspective

TW Ebbesen - Accounts of chemical research, 2016 - ACS Publications
Conspectus The notion that light and matter states can be hybridized the way s and p
orbitals are mixed is a concept that is not familiar to most chemists and material scientists …

Tilting a ground-state reactivity landscape by vibrational strong coupling

A Thomas, L Lethuillier-Karl, K Nagarajan… - Science, 2019 - science.org
Many chemical methods have been developed to favor a particular product in
transformations of compounds that have two or more reactive sites. We explored a different …