Chemistry of quantum spin liquids

JR Chamorro, TM McQueen, TT Tran - Chemical Reviews, 2020 - ACS Publications
Quantum spin liquids are an exciting playground for exotic physical phenomena and
emergent many-body quantum states. The realization and discovery of quantum spin liquid …

Néel-type skyrmion lattice with confined orientation in the polar magnetic semiconductor GaV4S8

I Kézsmárki, S Bordács, P Milde, E Neuber, LM Eng… - Nature materials, 2015 - nature.com
Following the early prediction of the skyrmion lattice (SkL)—a periodic array of spin vortices—
it has been observed recently in various magnetic crystals mostly with chiral structure …

Multiferroicity and skyrmions carrying electric polarization in GaV4S8

E Ruff, S Widmann, P Lunkenheimer, V Tsurkan… - Science …, 2015 - science.org
Skyrmions are whirl-like topological spin objects with high potential for future magnetic data
storage. A fundamental question that is relevant to both basic research and application is …

Optical, dielectric, and magnetoelectric properties of ferroelectric and antiferroelectric lacunar spinels

K Geirhos, S Reschke, S Ghara, S Krohns… - … status solidi (b), 2022 - Wiley Online Library
Lacunar spinels with a chemical formula of AM 4 X 8 form a populous family of narrow‐gap
semiconductors, which offer a fertile ground to explore correlation and quantum …

Ordering of hidden multipoles in spin-orbit entangled Ta chlorides

H Ishikawa, T Takayama, RK Kremer, J Nuss… - Physical Review B, 2019 - APS
Spin-orbit coupling of as large as a half eV for electrons in 5 d orbitals often gives rise to the
formation of spin-orbital entangled objects, with the effective total angular momentum J eff …

Featureless adaptive optimization accelerates functional electronic materials design

Y Wang, A Iyer, W Chen, JM Rondinelli - Applied Physics Reviews, 2020 - pubs.aip.org
Electronic materials that exhibit phase transitions between metastable states (eg, metal-
insulator transition materials with abrupt electrical resistivity transformations) are challenging …

Cluster Rearrangement by Chiral Charge Order in Lacunar Spinel GaNb4Se8

S Kitou, M Gen, Y Nakamura, Y Tokunaga… - Chemistry of …, 2024 - ACS Publications
Transition-metal atoms with d electrons sometimes form clusters in crystals, which
significantly affect the physical properties. Such a cluster formation frequently accompanies …

Resonating holes vs molecular spin-orbit coupled states in group-5 lacunar spinels

T Petersen, P Bhattacharyya, UK Rößler… - Nature …, 2023 - nature.com
The valence electronic structure of magnetic centers is one of the factors that determines the
characteristics of a magnet. This may refer to orbital degeneracy, as for j eff= 1/2 Kitaev …

Magnetic molecular orbitals in MnSi

Z **, Y Li, Z Hu, B Hu, Y Liu, K Iida, K Kamazawa… - Science …, 2023 - science.org
A large body of knowledge about magnetism is attained from models of interacting spins,
which usually reside on magnetic ions. Proposals beyond the ionic picture are uncommon …

Structural evolution and skyrmionic phase diagram of the lacunar spinel

EC Schueller, DA Kitchaev, JL Zuo, JD Bocarsly… - Physical Review …, 2020 - APS
In the AB 4 Q 8 lacunar spinels, the electronic structure is described on the basis of inter-and
intracluster interactions of tetrahedral B 4 clusters, and tuning these can lead to myriad …