Metal–Organic Frameworks for Electrocatalytic CO2 Reduction: From Catalytic Site Design to Microenvironment Modulation

C Zhang, Z Lin, L Jiao, HL Jiang - … Chemie International Edition, 2024 - Wiley Online Library
The electrochemical reduction of CO2 to high‐value carbon‐based chemicals provides a
sustainable approach to achieving an artificial carbon cycle. In the decade, metal–organic …

Beyond conventional: Role of chiral metal–organic frameworks in asymmetric scenarios

M Chafiq, A Chaouiki, J Ryu, YG Ko - Nano Today, 2024 - Elsevier
Over the past twenty years, a wide range of metal–organic frameworks (MOFs) has been
developed. MOFs exhibit interesting behaviors owing to the complex interactions between …

Chiral Ligand‐Decorated Rhodium Nanoparticles Incorporated in Covalent Organic Framework for Asymmetric Catalysis

J Yu, G Yang, ML Gao, H Wang… - Angewandte Chemie …, 2024 - Wiley Online Library
While metal nanoparticles (NPs) have demonstrated their great potential in catalysis,
introducing chiral microenvironment around metal NPs to achieve efficient conversion and …

Ratiometric Electrochemiluminescence of Zirconium Metal–Organic Framework as a Single Luminophore for Sensitive Detection of HPV-16 DNA

G Chen, W Dai, C Hu, H Zang, S Sun, S Zhen… - Analytical …, 2023 - ACS Publications
This study developed a new zirconium metal–organic framework (MOF) luminophore named
Zr-DPA@ TCPP with dual-emission electrochemiluminescence (ECL) characteristics at a …

Eu3+-Doped Anionic Zinc-Based Organic Framework Ratio Fluorescence Sensing Platform: Supersensitive Visual Identification of Prescription Drugs

W Liu, Y Huang, C Ji, CA Grimes, Z Liang, H Hu… - ACS …, 2024 - ACS Publications
Advanced techniques for both environmental and biological prescription drug monitoring are
of ongoing interest. In this work, a fluorescent sensor based on an Eu3+-doped anionic zinc …

Perfluoroalkyl‐Decorated Noble‐Metal‐Free MOFs for the Highly Efficient One‐Pot Four‐Component Coupling between Aldehydes, Amines, Alkynes, and Flue Gas …

F Yang, J Wang, Y Wang, B Yu, Y Cao, J Li… - Angewandte …, 2024 - Wiley Online Library
The non‐noble‐metal catalysed‐multicomponent reactions between flue gas CO2 and
cheap industrial raw stocks into high value‐added fine chemicals is a promising manner for …

Controlled synthesis of chiral carbon dots with high asymmetric catalytic properties and reproducibility for direct aldol reactions: The impact of functional groups of …

J Luo, S Wang, Y Ding, J Shen, C Xu - Carbon, 2024 - Elsevier
The controlled synthesis of carbon dots (CDs) has been a key scientific problem in the field
of catalysis. In this study, chiral CDs from different carbon sources were prepared using the …

Host–guest complexation‐induced chirality switching of pillararenes by perylene diimide‐based hexagonal metallacages

Y Hou, C Mu, Y Shi, Z Zhang, H Liu, Z Zhou, S Ling… - …, 2024 - Wiley Online Library
Chirality in confined nanospaces has brought some new insights into chirality transfer,
amplification, and chiroptical properties. However, chirality switching, which is a common …

Chemoenzymatic Catalysts Immobilized on Metal–Organic Layers for the Asymmetric Reduction of Unreactive Stereoisomers of Alkenes

W Wang, L Chen, Y Li, J Huang, BF Shi… - Chemistry of …, 2024 - ACS Publications
Chemoenzymatic catalytic systems developed in recent years have significantly expanded
the reaction types and substrate scope that can be achieved with enzymes but are limited by …

Highly Efficient Photocatalytic Divergent Decarbonylative Silylation with Cinnamaldehyde via a [Ru(dcbpy)(bpy)2]2+-Incorporated UiO-67 Framework

H Wang, B Qin, J Cai, Y Wu, C Zhao, X Bai… - ACS …, 2024 - ACS Publications
We herein develop an innovative approach for the decarbonylative silylation using a
molecular [Ru (dcbpy)(bpy) 2] 2+(dcbpy= 2, 2′-bipyridyl-5, 5′-dicarboxylic acid; bpy= 2 …