Precision polymer synthesis by controlled radical polymerization: Fusing the progress from polymer chemistry and reaction engineering

YN Zhou, JJ Li, TT Wang, YY Wu, ZH Luo - Progress in Polymer Science, 2022 - Elsevier
During the first 100 years of polymer science, controlled radical polymerization (also
recommended as reversible deactivation radical polymerization) is undoubtedly a …

Modeling and theoretical development in controlled radical polymerization

E Mastan, X Li, S Zhu - Progress in Polymer Science, 2015 - Elsevier
Controlled radical polymerization (CRP) systems have gained increasing interests for the
past two decades. Numerous publications may be found in the literature reporting …

State‐of‐the‐art and progress in method of moments for the model‐based reversible‐deactivation radical polymerization

YN Zhou, ZH Luo - Macromolecular Reaction Engineering, 2016 - Wiley Online Library
Reversible‐deactivation radical polymerization (RDRP) techniques have received lots of
interest for the past 20 years, not only owing to their simple, mild reaction conditions and …

A complete understanding of the reaction kinetics for the industrial production process of expandable polystyrene

L De Keer, PHM Van Steenberge, MF Reyniers… - AIChE …, 2017 - Wiley Online Library
For the industrial expandable polystyrene (EPS) process, the Predici software package is
successfully applied to demonstrate that the composite kt model is the most appropriate one …

History of nitroxide mediated polymerization in Canada

M Marić - The Canadian Journal of Chemical Engineering, 2021 - Wiley Online Library
Nitroxide mediated polymerization (NMP), sometimes known as stable free radical
polymerization (SFRP), is considered one of the main types of reversible deactivation radical …

Kinetic modeling as a tool to understand and improve the nitroxide mediated polymerization of styrene

L Bentein, DR D'hooge, MF Reyniers… - Macromolecular …, 2011 - Wiley Online Library
Kinetic modeling is used to obtain insight in the complex interplay between reaction rates
and obtained polymer properties in the SG1 and the TEMPO mediated bulk polymerization …

Artificial neural networks towards average properties targets in styrene ARGET-ATRP

G Banin, RP Vieira, LMF Lona - Chemical Engineering Journal, 2021 - Elsevier
The application of artificial neural networks (ANN) in the synthesis of polystyrene via ARGET-
ATRP was presented for the first time. In this research, it was utilized a deterministic …

Crosslinking nitroxide-mediated radical copolymerization of styrene with divinylbenzene

AJ Scott, A Nabifar, JC Hernández-Ortiz… - European Polymer …, 2014 - Elsevier
Results from the crosslinking kinetics of nitroxide-mediated radical polymerization (NMRP)
of styrene (STY) in the presence of a small amount of divinylbenzene (DVB) are presented …

Modeling of the Nitroxide‐Mediated Radical Copolymerization of Styrene and Divinylbenzene

JC Hernández‐Ortiz, E Vivaldo‐Lima… - Macromolecular …, 2009 - Wiley Online Library
A mathematical model for the copolymerization kinetics with crosslinking of vinyl/divinyl
monomers in the presence of nitroxide controllers has been developed and validated using …

Modelling of polymerization kinetics and molar mass development in the nitroxide‐mediated polymerization (NMP) of styrene in supercritical carbon dioxide using the …

P López‐Domínguez, M Ríos‐López… - … Canadian Journal of …, 2023 - Wiley Online Library
A mathematical model for polymerization kinetics and molar mass development in the
nitroxide‐mediated polymerization (NMP) of vinyl monomers in supercritical carbon dioxide …