Nitrous oxide, commonly known as “laughing gas”, is formed as a by-product in several
industrial processes. It is also readily available by thermal decomposition of ammonium …

The gaseous small molecules, CO2 and N2O, play important roles in climate change and
ozone layer depletion, and they hold promise as underutilized reagents and chemical …

In Nature, the four-electron reduction of O2 is catalyzed at preorganized multimetallic active
sites. These complex active sites often feature low-coordinate, redox-active metal centers …

The electronic features of gold‐aluminyl complexes have been thoroughly explored. Their
similarity with Group 14 dimetallenes and other metal‐aluminyl complexes suggests that …

Here we report the synthesis and characterization of diiron complexes containing triaryl N4
and N2S2 ligands derived from o-phenylenediamine. The complexes display significant …

The Fe n X n scaffold (X= p-block elements) occurs in many multimetallic metallaproteins
and metalloenzymes. Studies on synthetic complexes with a Fe2X2 core are of great interest …

Phosphazenes are a family of compounds containing the PQN motif. Although the nature of
the bonding in the PQN motif is controversial and might not involve a formal double bond in …

The activation of small molecules via multielectron redox processes offers promise in
mediating difficult transformations related to energy conversion processes. While molecular …

The synthesis of CpFe (CO) 2ECOCH2CO2R [E= S (1), Se (2); R= Me (a), Et (b)] was
achieved by treating (µ-E x)[CpFe (CO) 2] 2 (E= S, x= 2–4, Se, x= 1) with alkyl malonyl …

Herein we report the first example of a mononuclear uranium complex,[U4+ (NP (pip) 3) 4](1-
U), that selectively reduces dioxygen to produce a terminal oxo complex,[U6+ O (NP (pip) 3) …