Ethanol-to-butadiene: the reaction and its catalysts

G Pomalaza, PA Ponton, M Capron… - Catalysis Science & …, 2020 - pubs.rsc.org
Butadiene is a crucial chemical, notably for the manufacturing of car tires. The ethanol-to-
butadiene reaction has emerged as a promising solution to both environmental concerns …

[HTML][HTML] Catalytic conversion of bioethanol to value-added chemicals and fuels: A review

H **ang, R **n, N Prasongthum, P Natewong… - … Chemicals and Materials, 2022 - Elsevier
Bioethanol produced via valorisation of renewable biomass is of great interest to many
industries. The increased availability and decreased cost of bioethanol make it a promising …

Ethanol conversion to butadiene over isolated zinc and yttrium sites grafted onto dealuminated beta zeolite

L Qi, Y Zhang, MA Conrad, CK Russell… - Journal of the …, 2020 - ACS Publications
Zinc and Yttrium single sites were introduced into the silanol nests of dealuminated BEA
zeolite to produce Zn-DeAlBEA and Y-DeAlBEA. These materials were then investigated for …

Mechanistic insights into one-step catalytic conversion of ethanol to butadiene over bifunctional Zn–Y/beta zeolite

T Yan, W Dai, G Wu, S Lang, M Hunger, N Guan… - ACS …, 2018 - ACS Publications
Bifunctional Zn–Y/Beta catalyst was applied in the reaction mechanism study of the ethanol
to butadiene conversion to clarify the roles of Zn and Y functional sites in each individual …

Mechanism and Kinetics of Ethanol–Acetaldehyde Conversion to 1, 3-Butadiene over Isolated Lewis Acid La Sites in Silanol Nests in Dealuminated Beta Zeolite

Y Zhang, L Qi, Y Li, T Yang, DM Meira, C Dun… - ACS …, 2024 - ACS Publications
Biomass-derived ethanol (EtOH) and acetaldehyde (AcH) conversion to 1, 3-butadiene (1, 3-
BD) is an alternative process for 1, 3-BD production. The present investigation reports the …

Origin of active sites on silica–magnesia catalysts and control of reactive environment in the one-step ethanol-to-butadiene process

SH Chung, T Li, T Shoinkhorova, S Komaty… - Nature Catalysis, 2023 - nature.com
Wet-kneaded silica–magnesia is a benchmark catalyst for the one-step ethanol-to-butadiene
Lebedev process. Magnesium silicates, formed during wet kneading, have been proposed …

Mechanism and Kinetics of n-Butane Dehydrogenation to 1,3-Butadiene Catalyzed by Isolated Pt Sites Grafted onto ≡SiOZn–OH Nests in Dealuminated Zeolite Beta

Y Zhang, L Qi, B Leonhardt, AT Bell - ACS Catalysis, 2022 - ACS Publications
An interest in the on-purpose production of 1, 3-butadiene (1, 3-BD) has grown, as a
consequence of the decline in naphtha cracking for the production of ethene and propene …

Mechanistic and electronic insights into a working NiAu single-atom alloy ethanol dehydrogenation catalyst

G Giannakakis, P Kress, K Duanmu… - Journal of the …, 2021 - ACS Publications
Elucidation of reaction mechanisms and the geometric and electronic structure of the active
sites themselves is a challenging, yet essential task in the design of new heterogeneous …

Effect of the SiO2 support on the catalytic performance of Ag/ZrO2/SiO2 catalysts for the single-bed production of butadiene from ethanol

VL Dagle, MD Flake, TL Lemmon, JS Lopez… - Applied Catalysis B …, 2018 - Elsevier
Abstract A ternary Ag/ZrO 2/SiO 2 catalyst system was studied for single-step conversion of
ethanol to butadiene by varying the catalyst composition (Ag, Ir, or Pt metal component …

On the deactivation mechanism of zeolite catalyst in ethanol to butadiene conversion

T Yan, L Yang, W Dai, C Wang, G Wu, N Guan… - Journal of …, 2018 - Elsevier
Despite of extensive attention on the ethanol to butadiene (ETB) conversion, the catalyst
deactivation during ETB conversion is rarely investigated and poorly understood. Here, the …