Synchrotron radiation techniques and their application to actinide materials
Research on actinide materials, both basic and applied, has been greatly advanced by the
general techniques available from high-intensity photon beams from x-ray synchrotron …
general techniques available from high-intensity photon beams from x-ray synchrotron …
Covalency in Lanthanides. An X-ray Absorption Spectroscopy and Density Functional Theory Study of LnCl6x– (x = 3, 2)
Covalency in Ln–Cl bonds of O h-LnCl6 x–(x= 3 for Ln= CeIII, NdIII, SmIII, EuIII, GdIII; x= 2 for
Ln= CeIV) anions has been investigated, primarily using Cl K-edge X-ray absorption …
Ln= CeIV) anions has been investigated, primarily using Cl K-edge X-ray absorption …
X-ray Raman scattering: a hard X-ray probe of complex organic systems
This paper provides a review of the characterization of organic systems via X-ray Raman
scattering (XRS) and a step-by-step guidance for its application. We present the …
scattering (XRS) and a step-by-step guidance for its application. We present the …
Singlet magnetism in intermetallic unveiled by inelastic x-ray scattering
Using high resolution tender x-ray resonant inelastic scattering and hard x-ray nonresonant
inelastic scattering beyond the dipole limit we were able to detect electronic excitations in …
inelastic scattering beyond the dipole limit we were able to detect electronic excitations in …
Synthesis, characterization, and multielectron reduction chemistry of uranium supported by redox-active α-diimine ligands
Uranium compounds supported by redox-active α-diimine ligands, which have methyl
groups on the ligand backbone and bulky mesityl substituents on the nitrogen atoms …
groups on the ligand backbone and bulky mesityl substituents on the nitrogen atoms …
A high resolution and large solid angle x-ray Raman spectroscopy end-station at the Stanford Synchrotron Radiation Lightsource
We present a new x-ray Raman spectroscopy end-station recently developed, installed, and
operated at the Stanford Synchrotron Radiation Lightsource. The end-station is located at …
operated at the Stanford Synchrotron Radiation Lightsource. The end-station is located at …
Crystal Field Ground State of the Strongly Correlated Topological Insulator
We investigated the crystal-electric field ground state of the 4 f manifold in the strongly
correlated topological insulator SmB 6 using core-level nonresonant inelastic x-ray …
correlated topological insulator SmB 6 using core-level nonresonant inelastic x-ray …
Probing the 5f orbital contribution to the bonding in a U (V) ketimide complex
LA Seaman, G Wu, N Edelstein… - Journal of the …, 2012 - ACS Publications
Reaction of UCl4 with 5 equiv of Li (N CtBuPh) generates the homoleptic U (IV) ketimide
complex [Li (THF) 2][U (N CtBuPh) 5](1) in 71% yield. Similarly, reaction of UCl4 with 5 …
complex [Li (THF) 2][U (N CtBuPh) 5](1) in 71% yield. Similarly, reaction of UCl4 with 5 …
Direct bulk-sensitive probe of 5f symmetry in URu2Si2
The second-order phase transition into a hidden order phase in URu2Si2 goes along with
an order parameter that is still a mystery, despite 30 years of research. However, it is …
an order parameter that is still a mystery, despite 30 years of research. However, it is …
Emission spectroscopy of uranium (IV) compounds: a combined synthetic, spectroscopic and computational study
E Hashem, AN Swinburne, C Schulzke, RC Evans… - Rsc Advances, 2013 - pubs.rsc.org
Emission spectroscopy has been used for the first time in a spectroscopic study of a family of
uranium (IV) halide complexes in non-aqueous media. The room temperature electronic …
uranium (IV) halide complexes in non-aqueous media. The room temperature electronic …