Synchrotron radiation techniques and their application to actinide materials

R Caciuffo, GH Lander, G van der Laan - Reviews of Modern Physics, 2023 - APS
Research on actinide materials, both basic and applied, has been greatly advanced by the
general techniques available from high-intensity photon beams from x-ray synchrotron …

Covalency in Lanthanides. An X-ray Absorption Spectroscopy and Density Functional Theory Study of LnCl6x (x = 3, 2)

MW Löble, JM Keith, AB Altman… - Journal of the …, 2015 - ACS Publications
Covalency in Ln–Cl bonds of O h-LnCl6 x–(x= 3 for Ln= CeIII, NdIII, SmIII, EuIII, GdIII; x= 2 for
Ln= CeIV) anions has been investigated, primarily using Cl K-edge X-ray absorption …

X-ray Raman scattering: a hard X-ray probe of complex organic systems

R Georgiou, CJ Sahle, D Sokaras, S Bernard… - Chemical …, 2022 - ACS Publications
This paper provides a review of the characterization of organic systems via X-ray Raman
scattering (XRS) and a step-by-step guidance for its application. We present the …

Singlet magnetism in intermetallic unveiled by inelastic x-ray scattering

A Marino, M Sundermann, DS Christovam, A Amorese… - Physical Review B, 2023 - APS
Using high resolution tender x-ray resonant inelastic scattering and hard x-ray nonresonant
inelastic scattering beyond the dipole limit we were able to detect electronic excitations in …

Synthesis, characterization, and multielectron reduction chemistry of uranium supported by redox-active α-diimine ligands

SJ Kraft, UJ Williams, SR Daly, E J. Schelter… - Inorganic …, 2011 - ACS Publications
Uranium compounds supported by redox-active α-diimine ligands, which have methyl
groups on the ligand backbone and bulky mesityl substituents on the nitrogen atoms …

A high resolution and large solid angle x-ray Raman spectroscopy end-station at the Stanford Synchrotron Radiation Lightsource

D Sokaras, D Nordlund, TC Weng, RA Mori… - Review of Scientific …, 2012 - pubs.aip.org
We present a new x-ray Raman spectroscopy end-station recently developed, installed, and
operated at the Stanford Synchrotron Radiation Lightsource. The end-station is located at …

Crystal Field Ground State of the Strongly Correlated Topological Insulator

M Sundermann, H Yavaş, K Chen, DJ Kim, Z Fisk… - Physical review …, 2018 - APS
We investigated the crystal-electric field ground state of the 4 f manifold in the strongly
correlated topological insulator SmB 6 using core-level nonresonant inelastic x-ray …

Probing the 5f orbital contribution to the bonding in a U (V) ketimide complex

LA Seaman, G Wu, N Edelstein… - Journal of the …, 2012 - ACS Publications
Reaction of UCl4 with 5 equiv of Li (N CtBuPh) generates the homoleptic U (IV) ketimide
complex [Li (THF) 2][U (N CtBuPh) 5](1) in 71% yield. Similarly, reaction of UCl4 with 5 …

Direct bulk-sensitive probe of 5f symmetry in URu2Si2

M Sundermann, MW Haverkort… - Proceedings of the …, 2016 - National Acad Sciences
The second-order phase transition into a hidden order phase in URu2Si2 goes along with
an order parameter that is still a mystery, despite 30 years of research. However, it is …

Emission spectroscopy of uranium (IV) compounds: a combined synthetic, spectroscopic and computational study

E Hashem, AN Swinburne, C Schulzke, RC Evans… - Rsc Advances, 2013 - pubs.rsc.org
Emission spectroscopy has been used for the first time in a spectroscopic study of a family of
uranium (IV) halide complexes in non-aqueous media. The room temperature electronic …