Iron catalysis in organic synthesis

I Bauer, HJ Knölker - Chemical reviews, 2015 - ACS Publications
The present review “Iron Catalysis in Organic Synthesis” covers the literature until the end of
June 2014 and represents a comprehensive update of a previous article published by Bolm …

Reduction of nitro compounds using 3d-non-noble metal catalysts

D Formenti, F Ferretti, FK Scharnagl, M Beller - Chemical reviews, 2018 - ACS Publications
The reduction of nitro compounds to the corresponding amines is one of the most utilized
catalytic processes in the fine and bulk chemical industry. The latest development of …

Organic synthesis with the most abundant transition metal–iron: from rust to multitasking catalysts

S Rana, JP Biswas, S Paul, A Paik… - Chemical Society Reviews, 2021 - pubs.rsc.org
In industries and academic laboratories, several late transition metal-catalyzed prerequisite
reactions are widely performed during single and multistep synthesis. However, besides the …

Phthalocyanine metal complexes in catalysis

AB Sorokin - Chemical reviews, 2013 - ACS Publications
1. INTRODUCTION Phthalocyanine metal complexes 1, 2 (MPc's) are structurally related to
porphyrin complexes (Figure 1), which are widely used by nature in the active sites of …

Recent developments in the reduction of aromatic and aliphatic nitro compounds to amines

M Orlandi, D Brenna, R Harms, S Jost… - … Process Research & …, 2016 - ACS Publications
The reduction of the nitro group represents a powerful and widely used transformation that
allows to introducing an amino group in the molecule. New synthetic strategies for complex …

Advancement in methodologies for reduction of nitroarenes

HK Kadam, SG Tilve - RSC advances, 2015 - pubs.rsc.org
The importance of aryl amines as raw materials for various applications has spurred
extensive research in develo** economic processes for the reduction of nitroarenes …

Mechanistic Studies of the Reduction of Nitroarenes by NaBH4 or Hydrosilanes Catalyzed by Supported Gold Nanoparticles

S Fountoulaki, V Daikopoulou, PL Gkizis… - ACS …, 2014 - ACS Publications
Herein, we show that mesoporous titania-supported gold nanoparticle assemblies (Au/MTA)
catalyze the activation of NaBH4 and 1, 1, 3, 3-tetramethyl disiloxane (TMDS) compounds …

Synthetic and Mechanistic Studies into the Reductive Functionalization of Nitro Compounds Catalyzed by an Iron (salen) Complex

E Pocock, M Diefenbach, TM Hood… - Journal of the …, 2024 - ACS Publications
We report on the use of a simple, bench-stable [Fe (salen) 2]-μ-oxo precatalyst in the
reduction of nitro compounds. The reaction proceeds at room temperature across a range of …

Iron phthalocyanine as an efficient and versatile catalyst for N-alkylation of heterocyclic amines with alcohols: one-pot synthesis of 2-substituted benzimidazoles …

M Bala, PK Verma, U Sharma, N Kumar, B Singh - Green chemistry, 2013 - pubs.rsc.org
An efficient and versatile iron phthalocyanine catalyzed method has been developed for N-
alkylation of various amines with alcohols. Readily available alcohols were used as …

[PDF][PDF] In situ generated iron oxide nanocrystals as efficient and selective catalysts for the reduction of nitroarenes using a continuous flow method

D Cantillo, M Baghbanzadeh… - Angewandte Chemie …, 2012 - academia.edu
Functionalized anilines are industrially important intermediates in the preparation of
pharmaceuticals, agrochemicals, dyes, and pigments. The most commonly used method for …