Molecular magnetism, quo vadis? A historical perspective from a coordination chemist viewpoint☆

J Ferrando-Soria, J Vallejo, M Castellano… - Coordination Chemistry …, 2017 - Elsevier
Molecular magnetism has travelled a long way from the pioneering studies on electron
exchange and double exchange or spin crossover and valence tautomerism in small …

Creating designer quantum states of matter atom-by-atom

AA Khajetoorians, D Wegner, AF Otte, I Swart - Nature Reviews Physics, 2019 - nature.com
Advances in high-resolution and spin-resolved scanning tunnelling microscopy, as well as
atomic-scale manipulation, have enabled the bottom-up, atom-by-atom creation and …

Electron spin resonance of single iron phthalocyanine molecules and role of their non-localized spins in magnetic interactions

X Zhang, C Wolf, Y Wang, H Aubin, T Bilgeri… - Nature Chemistry, 2022 - nature.com
Electron spin resonance (ESR) spectroscopy is a crucial tool, through spin labelling, in
investigations of the chemical structure of materials and of the electronic structure of …

Strategies toward high-temperature lanthanide-based single-molecule magnets

L Ungur, LF Chibotaru - Inorganic Chemistry, 2016 - ACS Publications
Lanthanide-based single-molecule magnets are leading materials for achieving
magnetization blocking at the level of one molecule. In this paper, we examine the physical …

Quantum tunnelling of the magnetization in a monolayer of oriented single-molecule magnets

M Mannini, F Pineider, C Danieli, F Totti, L Sorace… - Nature, 2010 - nature.com
A fundamental step towards atomic-or molecular-scale spintronic devices has recently been
made by demonstrating that the spin of an individual atom deposited on a surface, or of a …

Coherent spin manipulation of individual atoms on a surface

K Yang, W Paul, SH Phark, P Willke, Y Bae, T Choi… - Science, 2019 - science.org
Achieving time-domain control of quantum states with atomic-scale spatial resolution in
nanostructures is a long-term goal in quantum nanoscience and spintronics. Here, we …

Measurement of fast electron spin relaxation times with atomic resolution

S Loth, M Etzkorn, CP Lutz, DM Eigler, AJ Heinrich - Science, 2010 - science.org
Single spins in solid-state systems are often considered prime candidates for the storage of
quantum information, and their interaction with the environment the main limiting factor for …

Slow magnetic relaxation in a family of trigonal pyramidal iron (II) pyrrolide complexes

WH Harman, TD Harris, DE Freedman… - Journal of the …, 2010 - ACS Publications
We present a family of trigonal pyramidal iron (II) complexes supported by tris (pyrrolyl-α-
methyl) amine ligands of the general formula [M (solv) n][(tpaR) Fe](M= Na, R= tert-butyl (1) …

Evidence for spinarons in Co adatoms

F Friedrich, A Odobesko, J Bouaziz, S Lounis, M Bode - Nature Physics, 2024 - nature.com
Cobalt atoms on the (111) surfaces of noble metals are considered to be prototypical
systems for the Kondo effect in scanning tunnelling microscopy experiments. Recent first …

Spin excitations and correlations in scanning tunneling spectroscopy

M Ternes - New Journal of Physics, 2015 - iopscience.iop.org
In recent years inelastic spin-flip spectroscopy using a low-temperature scanning tunneling
microscope has been a very successful tool for studying not only individual spins but also …