Lanthanide single-molecule magnets

DN Woodruff, REP Winpenny, RA Layfield - Chemical reviews, 2013 - ACS Publications
In the early 1990s, great excitement followed the discovery that a molecular transition metal
coordination compound could, at liquid-helium temperatures, retain magnetization for long …

Measuring molecular magnets for quantum technologies

E Moreno-Pineda, W Wernsdorfer - Nature Reviews Physics, 2021 - nature.com
Single-molecule magnets (SMMs) have been proposed for applications in high-density
storage, quantum simulation, quantum computing and spintronics applications. Bulk …

Exploiting single-ion anisotropy in the design of f-element single-molecule magnets

JD Rinehart, JR Long - Chemical Science, 2011 - pubs.rsc.org
Scientists have long employed lanthanide elements in the design of materials with
extraordinary magnetic properties, including the strongest magnets known, SmCo5 and …

AN23– Radical-Bridged Terbium Complex Exhibiting Magnetic Hysteresis at 14 K

JD Rinehart, M Fang, WJ Evans… - Journal of the American …, 2011 - ACS Publications
The synthesis and magnetic properties of three new N23–radical-bridged dilanthanide
complexes,{[(Me3Si) 2N] 2 (THF) Ln} 2 (μ-η2: η2-N2)−(Ln= Tb, Ho, Er), are reported. All …

Rare-earth based tetrapyrrolic sandwiches: chemistry, materials and applications

AG Martynov, Y Horii, K Katoh, Y Bian, J Jiang… - Chemical Society …, 2022 - pubs.rsc.org
The unique properties of natural tetrapyrrolic compounds have inspired the rapid growth of
research interest in the design and synthesis of artificial porphyrinoids and their metal …

Radical ligand-containing single-molecule magnets

S Demir, IR Jeon, JR Long, TD Harris - Coordination Chemistry Reviews, 2015 - Elsevier
Single-molecule magnets represent the ultimate size limit for spin-based information storage
and processing; however, such applications require large spin relaxation barriers and …

Shining new light on multifunctional lanthanide single‐molecule magnets

R Marin, G Brunet, M Murugesu - … Chemie International Edition, 2021 - Wiley Online Library
Single‐molecule magnets (SMMs) are at the forefront of new technological advances in
quantum information processing and spintronics. Despite the recent impressive …

Magnetic blocking in a linear iron(I) complex

JM Zadrozny, DJ **ao, M Atanasov, GJ Long… - Nature …, 2013 - nature.com
Single-molecule magnets that contain one spin centre may represent the smallest possible
unit for spin-based computational devices. Such applications, however, require the …

A linear cobalt (II) complex with maximal orbital angular momentum from a non-Aufbau ground state

PC Bunting, M Atanasov, E Damgaard-Møller… - Science, 2018 - science.org
INTRODUCTION The magnetic properties of a single metal center are determined by a
combination of its total spin S and orbital angular momentum L. Orbital angular momentum …

Computational design of magnetic molecules and their environment using quantum chemistry, machine learning and multiscale simulations

A Lunghi, S Sanvito - Nature Reviews Chemistry, 2022 - nature.com
Having served as a playground for fundamental studies on the physics of d and f electrons
for almost a century, magnetic molecules are now becoming increasingly important for …