Controlled/living radical polymerization: Features, developments, and perspectives

WA Braunecker, K Matyjaszewski - Progress in polymer science, 2007 - Elsevier
Recent mechanistic developments in the field of controlled/living radical polymerization
(CRP) are reviewed. Particular emphasis is placed on structure–reactivity correlations and …

Advanced materials by atom transfer radical polymerization

K Matyjaszewski - Advanced Materials, 2018 - Wiley Online Library
Atom transfer radical polymerization (ATRP) has been successfully employed for the
preparation of various advanced materials with controlled architecture. New catalysts with …

Atom transfer radical polymerization (ATRP): current status and future perspectives

K Matyjaszewski - Macromolecules, 2012 - ACS Publications
Current status and future perspectives in atom transfer radical polymerization (ATRP) are
presented. Special emphasis is placed on mechanistic understanding of ATRP, recent …

Macromolecular engineering by atom transfer radical polymerization

K Matyjaszewski, NV Tsarevsky - Journal of the American …, 2014 - ACS Publications
This Perspective presents recent advances in macromolecular engineering enabled by
ATRP. They include the fundamental mechanistic and synthetic features of ATRP with …

Photomediated controlled radical polymerization

X Pan, MA Tasdelen, J Laun, T Junkers, Y Yagci… - Progress in Polymer …, 2016 - Elsevier
Photomediated controlled radical polymerization is a versatile method to prepare, under
mild conditions, various well-defined polymers with complex architecture, such as block and …

Catalytic hydrogen atom transfer to alkenes: a roadmap for metal hydrides and radicals

SL Shevick, CV Wilson, S Kotesova, D Kim… - Chemical …, 2020 - pubs.rsc.org
Hydrogen atom transfer from a metal hydride (MHAT) has emerged as a powerful, if
puzzling, technique in chemical synthesis. In catalytic MHAT reactions, earth-abundant …

“Green” atom transfer radical polymerization: from process design to preparation of well-defined environmentally friendly polymeric materials

NV Tsarevsky, K Matyjaszewski - Chemical reviews, 2007 - ACS Publications
Virtually every branch of science, technology, and art uses a plethora of polymeric materials.
These include not only “pure” linear, branched, or cross-linked (gels, rubbers, etc.) polymers …

Externally controlled atom transfer radical polymerization

X Pan, M Fantin, F Yuan, K Matyjaszewski - Chemical Society Reviews, 2018 - pubs.rsc.org
Spatial and temporal regulations of ATRP by external stimuli are presented. Various ATRP
techniques, eATRP, photoATRP, and mechanoATRP, are controlled by electrical current …

Atom transfer radical polymerization: billion times more active catalysts and new initiation systems

TG Ribelli, F Lorandi, M Fantin… - Macromolecular rapid …, 2019 - Wiley Online Library
Approaching 25 years since its invention, atom transfer radical polymerization (ATRP) is
established as a powerful technique to prepare precisely defined polymeric materials. This …

Nitroxides: applications in synthesis and in polymer chemistry

L Tebben, A Studer - Angewandte Chemie International Edition, 2011 - Wiley Online Library
This Review describes the application of nitroxides to synthesis and polymer chemistry. The
synthesis and physical properties of nitroxides are discussed first. The largest section …