The fourth ferroic order: Current status on ferrotoroidic materials

S Gnewuch, EE Rodriguez - Journal of Solid State Chemistry, 2019 - Elsevier
We review the topic of ferrotoroidicty and the inorganic solids proposed to exhibit this most
elusive category of primary ferroic orders. We first define how ferrotoroidic order fits in with …

A pyroxene-based quantum magnet with multiple magnetization plateaus

L **, S Peng, AN Rutherford, X Xu, D Ni, C Yang… - Science …, 2024 - science.org
Pyroxenes (AMX2O6) consisting of infinite one-dimensional edge-sharing MO6 chains and
bridging XO4 tetrahedra are fertile ground for finding quantum materials. Thus, here, we …

Thermodynamic properties of the new multiferroic material (NH4) 2 [FeCl5 (H2O)]

M Ackermann, D Brüning, T Lorenz… - New Journal of …, 2013 - iopscience.iop.org
Abstract (NH 4) 2 [FeCl 5 (H 2 O)], a member of the family of antiferromagnetic A 2 [FeX 5 (H
2 O)] compounds (X= halide ion and A= alkali metal or ammonium ion) is classified as a new …

Structural, mechanical, electronic and optical properties of half-metallic XFeSi2O6 (X= Li, Na, K) clinopyroxenes: A first-principles investigation

NA Shahed, S Khanom, MK Hossain… - Materials Science and …, 2021 - Elsevier
Pyroxene structures are ferromagnetic silicates that are found in abundance in the Earth's
crust and upper mantle, which crystallizes in orthorhombic and monoclinic systems. Here …

One-dimensional short-range magnetic correlations in the magnetoelectric pyroxene

L Ding, CV Colin, C Darie, J Robert, F Gay, P Bordet - Physical Review B, 2016 - APS
We have investigated the magnetic and magnetoelectric properties of CaMnGe 2 O 6 by
means of powder neutron diffraction, magnetic susceptibility, heat capacity, and electrical …

First-principles investigation of half-metallic CaTGe2O6 (T= Mn, Fe, Co) clinopyroxenes: Potential for spintronics and optoelectronics applications

T Akter, J Islam, K Hossain, RA Rabu - Heliyon, 2025 - cell.com
Clinopyroxene is a subgroup of pyroxene that is found in a variety of igneous and
metamorphic rocks. This study investigates the structural, mechanical, electronic, optical …

Magnetic pyroxenes and : Dimensionality crossover in a nonfrustrated Heisenberg model

O Janson, G Nénert, M Isobe, Y Skourski, Y Ueda… - Physical Review B, 2014 - APS
The magnetism of magnetoelectric S= 3 2 pyroxenes LiCrSi 2 O 6 and LiCrGe 2 O 6 is
studied by density functional theory calculations, quantum Monte Carlo (QMC) simulations …

Unraveling the complex magnetic structure of multiferroic pyroxene : A combined experimental and theoretical study

L Ding, P Manuel, DD Khalyavin, F Orlandi, AA Tsirlin - Physical Review B, 2018 - APS
Magnetic order and the underlying magnetic model of the multiferroic pyroxene NaFeGe 2 O
6 are systematically investigated by neutron powder diffraction, thermodynamic …

The first-principle study on structural, mechanical, electronic and optical properties of half-metallic CaMSi2O6 (M= Co, Fe, Mn) clinopyroxenes

F Fakhera, NA Shahed, S Khanom, MK Hossain… - Computational …, 2022 - Elsevier
Ca-based pyroxene structures have gained significant attention due to the higher
abundances of calcium in the earth's crust and relatively easy synthesis process. Here, we …

Magnetoelectric coupling in the mixed erythrosiderite

D Brüning, T Fröhlich, M Langenbach, T Leich… - Physical Review B, 2020 - APS
We present a study of the dielectric, structural, and magnetic properties of the multiferroic or
linear magnetoelectric substitution series [(NH 4) 1− x K x] 2 [Fe Cl 5 (H 2 O)]. Pyroelectric …