Control, modulation, and analytical descriptions of vibrational strong coupling

BS Simpkins, AD Dunkelberger, I Vurgaftman - Chemical Reviews, 2023 - ACS Publications
Here, we review the design of optical cavities, transient and modulated responses, and
theoretical models relevant to vibrational strong coupling (VSC). While planar Fabry–Perot …

Molecular polaritonics: Chemical dynamics under strong light–matter coupling

TE Li, B Cui, JE Subotnik, A Nitzan - Annual review of physical …, 2022 - annualreviews.org
Chemical manifestations of strong light–matter coupling have recently been a subject of
intense experimental and theoretical studies. Here we review the present status of this field …

Boosting Light− Matter Interactions in Plasmonic Nanogaps

Y Li, W Chen, X He, J Shi, X Cui, J Sun… - Advanced …, 2024 - Wiley Online Library
Plasmonic nanogaps in strongly coupled metal nanostructures can confine light to
nanoscale regions, leading to huge electric field enhancement. This unique capability …

Something from nothing: linking molecules with virtual light

MS Rider, WL Barnes - Contemporary Physics, 2021 - Taylor & Francis
A new research field is emerging in which ensembles of molecules are collectively
hybridised with light in a process known as strong coupling. This hybridisation leads to the …

Complementary Surface‐Enhanced Raman Scattering (SERS) and IR Absorption Spectroscopy (SEIRAS) with Nanorods‐on‐a‐Mirror

E Oksenberg, I Shlesinger, G Tek… - Advanced Functional …, 2023 - Wiley Online Library
The surface‐enhanced counterparts of Raman scattering (SERS) and infrared (IR)
absorption (SEIRAS) are commonly used to probe and identify nanoscale matter and small …

Vibrational coupling of water from weak to ultrastrong coupling regime via cavity mode tuning

T Fukushima, S Yoshimitsu… - The Journal of Physical …, 2021 - ACS Publications
Vibrational strong coupling is an emerging method for modulation of ground-state molecular
properties. Spectroscopic information about the vibrational coupling state is essential for …

Raman probing the local ultrastrong coupling of vibrational plasmon polaritons on metallic gratings

R Arul, K Menghrajani, MS Rider, R Chikkaraddy… - Physical Review Letters, 2023 - APS
Strong coupling of molecular vibrations with light creates polariton states, enabling control
over many optical and chemical properties. However, the near-field signatures of strong …

Probing Vibrational Strong Coupling of Molecules with Wavelength‐Modulated Raman Spectroscopy

KS Menghrajani, M Chen, K Dholakia… - Advanced Optical …, 2022 - Wiley Online Library
Raman spectroscopy is a powerful technique that enables fingerprinting of materials,
molecules, and chemical environments by probing vibrational resonances. In many …

[HTML][HTML] Spontaneous Raman scattering from vibrational polaritons is obscured by reservoir states

B Cohn, T Filippov, E Ber, L Chuntonov - The Journal of Chemical …, 2023 - pubs.aip.org
Vibrational strong coupling results from the interaction between optically allowed molecular
vibrational excitations and the resonant mode of an infrared cavity. Strong coupling leads to …

Chasing vibro-polariton fingerprints in infrared and Raman spectra using surface lattice resonances on extended metasurfaces

F Verdelli, JJPM Schulpen, A Baldi… - The Journal of Physical …, 2022 - ACS Publications
We present an experimental investigation of vibrational strong coupling of C═ O bonds in
poly (methyl methacrylate) to surface lattice resonances (SLRs) on arrays of gold particles in …