Polyhalogen and polyinterhalogen anions from fluorine to iodine
K Sonnenberg, L Mann, FA Redeker… - Angewandte Chemie …, 2020 - Wiley Online Library
This Review deals with the evolving field of polyhalogen chemistry, specifically polyhalogen
anions (polyhalides). In addition to a historical outline, current progress in synthetic …
anions (polyhalides). In addition to a historical outline, current progress in synthetic …
Polyhalogen‐und Polyinterhalogen‐Anionen von Fluor bis Iod
K Sonnenberg, L Mann, FA Redeker… - Angewandte …, 2020 - Wiley Online Library
Dieser Aufsatz widmet sich dem wachsenden Gebiet der Polyhalogen‐Chemie und
insbesondere den Polyhalogen‐Anionen (Polyhalogenide). Neben einem historischen …
insbesondere den Polyhalogen‐Anionen (Polyhalogenide). Neben einem historischen …
Br 2 F 7− and Br 3 F 10−: peculiar anions showing μ 2-and μ 3-bridging F-atoms
RbCl and CsCl react with BrF3 yielding the corresponding decafluoridotribromates (III),
MBr3F10 (M= Rb, Cs), which were structurally characterized for the first time. The Br3F10 …
MBr3F10 (M= Rb, Cs), which were structurally characterized for the first time. The Br3F10 …
[Br 4 F 21]−–a unique molecular tetrahedral interhalogen ion containing a μ 4-bridging fluorine atom surrounded by BrF 5 molecules
The reaction of [NMe4][BrF6] with an excess of BrF5 leads to the compound [NMe4][Br4F21]·
BrF5. It features molecular [(μ4-F)(BrF5) 4]− anions of tetrahedron-like shape containing …
BrF5. It features molecular [(μ4-F)(BrF5) 4]− anions of tetrahedron-like shape containing …
RbBrF4 Revisited
Rubidium tetrafluoridobromate (III) was synthesized and structurally characterized. The
compound is isotypic to sodium and potassium tetrafluoridobromate (III), and crystallizes in …
compound is isotypic to sodium and potassium tetrafluoridobromate (III), and crystallizes in …
Synthesis and Characterization of [Br3][MF6] (M=Sb, Ir), as well as Quantum Chemical Study of [Br3]+ Structure, Chemical Bonding, and Relativistic Effects Compared with [XBr2]+ (X=Br, I …
Abstract [Br3][SbF6] and [Br3][IrF6] were synthesized by interaction of BrF3 with Sb2O3 or
iridium metal, respectively. The former compound crystallizes in the orthorhombic space …
iridium metal, respectively. The former compound crystallizes in the orthorhombic space …
Conductivity and Redox Potentials of Ionic Liquid Trihalogen Monoanions [X3]−, [XY2]−, and [BrF4]− (X=Cl, Br, I and Y=Cl, Br)
TA Gully, P Voßnacker, JR Schmid, H Beckers… - …, 2021 - Wiley Online Library
The ionic liquid (IL) trihalogen monoanions [N2221][X3]− and [N2221][XY2]−([N2221]+=
triethylmethylammonium, X= Cl, Br, I, Y= Cl, Br) were investigated electrochemically via …
triethylmethylammonium, X= Cl, Br, I, Y= Cl, Br) were investigated electrochemically via …
Synthesis and Characterization of Barium Tetrafluoridobromate(III) Ba(BrF4)2
Alkali and alkaline earth metal tetrafluoridobromates MIBrF4, MII (BrF4) 2 (MI= Na–Cs, MII=
Sr, Ba) can be synthesized from the respective fluorides and BrF3. The reaction of BaF2 with …
Sr, Ba) can be synthesized from the respective fluorides and BrF3. The reaction of BaF2 with …
From Square‐Planar [ICl4]− to Novel Chloroiodates(III)? A Systematic Experimental and Theoretical Investigation of Their Ionic Liquids
B Burgenmeister, K Sonnenberg… - … A European Journal, 2017 - Wiley Online Library
A systematic investigation on the existence of chloroiodates formed by reaction of Cl− with
I2Cl6, apart from the well‐known [ICl4]−, namely [I2Cl7]− and [I3Cl10]−, was undertaken by …
I2Cl6, apart from the well‐known [ICl4]−, namely [I2Cl7]− and [I3Cl10]−, was undertaken by …
The Interhalogen Cations [Br2F5]+ and [Br3F8]+
The synthesis and characterization of unique polyhalogen cations containing μ‐bridging
fluorine atoms are reported. The [Br2F5]+ cation features a symmetric [F2Br–μ‐F–BrF2] …
fluorine atoms are reported. The [Br2F5]+ cation features a symmetric [F2Br–μ‐F–BrF2] …