Chemical reactivity under nanoconfinement

AB Grommet, M Feller, R Klajn - Nature nanotechnology, 2020 - nature.com
Confining molecules can fundamentally change their chemical and physical properties.
Confinement effects are considered instrumental at various stages of the origins of life, and …

Supramolecular assemblies on surfaces: nanopatterning, functionality, and reactivity

DP Goronzy, M Ebrahimi, F Rosei, Arramel, Y Fang… - ACS …, 2018 - ACS Publications
Understanding how molecules interact to form large-scale hierarchical structures on
surfaces holds promise for building designer nanoscale constructs with defined chemical …

Decacene: on‐surface generation

J Krüger, F García, F Eisenhut, D Skidin… - Angewandte Chemie …, 2017 - Wiley Online Library
Acenes are intriguing molecules with unique electronic properties. The difficulties in their
preparation owing to low stability under ambient conditions are apparent because …

Higher acenes by on‐surface dehydrogenation: from heptacene to undecacene

R Zuzak, R Dorel, M Kolmer… - Angewandte Chemie …, 2018 - Wiley Online Library
A unified approach to the synthesis of the series of higher acenes up to previously
unreported undecacene has been developed through the on‐surface dehydrogenation of …

Dodecacene generated on surface: reopening of the energy gap

F Eisenhut, T Kühne, F García, S Fernández… - ACS …, 2019 - ACS Publications
The acene series represents a model system to investigate the intriguing electronic
properties of extended π-electron structures in the one-dimensional limit, which are …

Covalent‐Bond Formation via On‐Surface Chemistry

PA Held, H Fuchs, A Studer - Chemistry–A European Journal, 2017 - Wiley Online Library
In this Review article pioneering work and recent achievements in the emerging research
area of on‐surface chemistry is discussed. On‐surface chemistry, sometimes also called two …

Unusual stabilization of larger acenes and heteroacenes

M Müller, L Ahrens, V Brosius, J Freudenberg… - Journal of Materials …, 2019 - pubs.rsc.org
The larger acenes and heteroacenes (> pentacenes) are attractive, yet sensitive materials;
several strategies were developed to stabilize such species.“Classic” approaches employ …

On‐Surface Synthesis and Determination of the Open‐Shell Singlet Ground State of Tridecacene

R Zuzak, M Kumar, O Stoica… - Angewandte Chemie …, 2024 - Wiley Online Library
The character of the electronic structure of acenes has been the subject of longstanding
discussion. However, convincing experimental evidence of their open‐shell character has …

Nonacene generated by on-surface dehydrogenation

R Zuzak, R Dorel, M Krawiec, B Such, M Kolmer… - ACS …, 2017 - ACS Publications
The on-surface synthesis of nonacene has been accomplished by dehydrogenation of an air-
stable partially saturated precursor, which could be aromatized by using a combined …

On‐Surface Reactions

R Lindner, A Kühnle - ChemPhysChem, 2015 - Wiley Online Library
On‐surface synthesis constitutes a rapidly growing field of research due to its promising
application for creating stable molecular structures on surfaces. While self‐assembled …