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Chemical reactivity under nanoconfinement
Confining molecules can fundamentally change their chemical and physical properties.
Confinement effects are considered instrumental at various stages of the origins of life, and …
Confinement effects are considered instrumental at various stages of the origins of life, and …
Supramolecular assemblies on surfaces: nanopatterning, functionality, and reactivity
Understanding how molecules interact to form large-scale hierarchical structures on
surfaces holds promise for building designer nanoscale constructs with defined chemical …
surfaces holds promise for building designer nanoscale constructs with defined chemical …
Decacene: on‐surface generation
Acenes are intriguing molecules with unique electronic properties. The difficulties in their
preparation owing to low stability under ambient conditions are apparent because …
preparation owing to low stability under ambient conditions are apparent because …
Higher acenes by on‐surface dehydrogenation: from heptacene to undecacene
A unified approach to the synthesis of the series of higher acenes up to previously
unreported undecacene has been developed through the on‐surface dehydrogenation of …
unreported undecacene has been developed through the on‐surface dehydrogenation of …
Dodecacene generated on surface: reopening of the energy gap
F Eisenhut, T Kühne, F García, S Fernández… - ACS …, 2019 - ACS Publications
The acene series represents a model system to investigate the intriguing electronic
properties of extended π-electron structures in the one-dimensional limit, which are …
properties of extended π-electron structures in the one-dimensional limit, which are …
Covalent‐Bond Formation via On‐Surface Chemistry
In this Review article pioneering work and recent achievements in the emerging research
area of on‐surface chemistry is discussed. On‐surface chemistry, sometimes also called two …
area of on‐surface chemistry is discussed. On‐surface chemistry, sometimes also called two …
Unusual stabilization of larger acenes and heteroacenes
The larger acenes and heteroacenes (> pentacenes) are attractive, yet sensitive materials;
several strategies were developed to stabilize such species.“Classic” approaches employ …
several strategies were developed to stabilize such species.“Classic” approaches employ …
On‐Surface Synthesis and Determination of the Open‐Shell Singlet Ground State of Tridecacene
The character of the electronic structure of acenes has been the subject of longstanding
discussion. However, convincing experimental evidence of their open‐shell character has …
discussion. However, convincing experimental evidence of their open‐shell character has …
Nonacene generated by on-surface dehydrogenation
The on-surface synthesis of nonacene has been accomplished by dehydrogenation of an air-
stable partially saturated precursor, which could be aromatized by using a combined …
stable partially saturated precursor, which could be aromatized by using a combined …
On‐Surface Reactions
R Lindner, A Kühnle - ChemPhysChem, 2015 - Wiley Online Library
On‐surface synthesis constitutes a rapidly growing field of research due to its promising
application for creating stable molecular structures on surfaces. While self‐assembled …
application for creating stable molecular structures on surfaces. While self‐assembled …