Halide Salts Alleviate TMSOK Inhibition in Suzuki–Miyaura Cross-Couplings

Y Shi, JS Derasp, SM Guzman, BO Patrick… - ACS catalysis, 2024 - ACS Publications
The Suzuki–Miyaura cross-coupling (SMC) remains one of the most widely used
transformations available to chemists. Recently, robust new conditions achieving rapid …

Suzuki–Miyaura Cross-Couplings of Alkylboranes: Transmetalation Studies and Synthesis of Model Organopalladium Pretransmetalation Species

A Olding, CC Ho, NT Lucas, BF Yates, AJ Canty… - ACS …, 2024 - ACS Publications
This report investigates the transmetalation of B-alkyl-9-borabicyclo [3.3. 1] nonane (B-alkyl-
9-BBN) coupling partners in Csp2–Csp3 Suzuki–Miyaura (SM) reactions. Kinetically stable …

Bulky phosphine ligands promote palladium-catalyzed protodeboronation

CT Ser, H Hao, S Pablo-García, K Jorner, S Li… - 2025 - chemrxiv.org
The Suzuki-Miyaura cross-coupling reaction is plagued by protodeboronation, an
undesirable side reaction with water that consumes the boronic acid derivatives required for …

Oxalyl Monoamide Ligand-Promoted Palladium-Catalyzed Suzuki Coupling Reactions in Aqueous Media at Low Doses

Y Xue, L Yanling, C **a, Z **aoyu, W Ailing, L Hailong - Acta Chimica Sinica - sioc-journal.cn
This article introduces a practical and environmentally friendly low-dose palladium-
catalyzed Suzuki coupling reaction system, utilizing simple oxalyl monoamines as ligands …

Ruphos Pd G4: A Catalyst for Suzuki-Miyaura Coupling Reactions Involving 1, 2, 4-Oxadiazoles

A Verma, D Kumar, S Singh, K Bandyopadhyay… - Ruphos Pd G - papers.ssrn.com
Abstract The 1, 2, 4-oxadiazole motif is highly significant in biological studies. An efficient
Suzuki-Miyaura coupling methodology has been developed, catalyzed by RuPhos Pd G4 …