Bottlebrush networks: a primer for advanced architectures

BR Clarke, CL Witt, M Ilton, AJ Crosby… - Angewandte …, 2024‏ - Wiley Online Library
Bottlebrush networks (BBNs) are an exciting new class of materials with interesting physical
properties derived from their unique architecture. While great strides have been made in our …

A review of computational studies of bottlebrush polymers

E Mohammadi, SY Joshi, SA Deshmukh - Computational Materials Science, 2021‏ - Elsevier
Bottlebrush polymers (BBPs) are a class of grafted polymers, which have attracted much
attention due to their wide range of novel applications. The properties of these grafted …

Tunable structural color of bottlebrush block copolymers through direct-write 3D printing from solution

BB Patel, DJ Walsh, DH Kim, J Kwok, B Lee… - Science …, 2020‏ - science.org
Additive manufacturing of functional materials is limited by control of microstructure and
assembly at the nanoscale. In this work, we integrate nonequilibrium self-assembly with …

Bottlebrush Block Copolymers at the Interface of Immiscible Liquids: Adsorption and Lateral Packing

HG Seong, Z **, Z Chen, M Hu, T Emrick… - Journal of the …, 2024‏ - ACS Publications
Amphiphilic bottlebrush block copolymers (BBCPs), having a hydrophilic bottlebrush
polymer (BP) linked covalently to a hydrophobic BP, were found to segregate to liquid–liquid …

Bottlebrush polymers at liquid interfaces: Assembly dynamics, mechanical properties, and all-liquid printed constructs

HG Seong, Z Fink, Z Chen, T Emrick, TP Russell - ACS nano, 2023‏ - ACS Publications
Bottlebrush polymer surfactants (BPSs), formed by the interfacial interactions between
bottlebrush polymers (BPs) with poly (acrylic acid) side chains dissolved in an aqueous …

Materials design of highly branched bottlebrush polymers at the intersection of modeling, synthesis, processing, and characterization

T Pan, S Dutta, Y Kamble, BB Patel… - Chemistry of …, 2022‏ - ACS Publications
Highly branched “bottlebrush” polymers are a class of macromolecules characterized by
side chains that are densely grafted from a backbone that is typically linear. Their unique …

Topologically precise and discrete bottlebrush polymers: synthesis, characterization, and Structure–Property relationships

ND Ogbonna, M Dearman, CT Cho, B Bharti, AJ Peters… - JACS Au, 2022‏ - ACS Publications
As the complexity of polymer structure grows, so do the challenges for develo** an
accurate understanding of their structure–property relationships. Here, the synthesis of …

Interface-dependent aggregation-induced delayed fluorescence in bottlebrush polymer nanofibers

CM Tonge, ZM Hudson - Journal of the American Chemical …, 2019‏ - ACS Publications
Bottlebrush copolymers provide a covalent route to multicompartment nanomaterials that
remain nanosegregated regardless of environmental conditions. This is particularly …

Engineering of molecular geometry in bottlebrush polymers

DJ Walsh, S Dutta, CE Sing, D Guironnet - Macromolecules, 2019‏ - ACS Publications
Bottlebrush polymers are large cylindrical macromolecules, where a molecular “width”
emerges from a large number of side chains densely attached to a central backbone. The …

Relationship between graft density and the dilute solution structure of bottlebrush polymers: an inter-chemistry comparison and scaling analysis

DF Sunday, AB Burns, TB Martin, AB Chang… - …, 2023‏ - ACS Publications
Bottlebrush polymers are an important class of materials which consist of side chains grafted
along a linear backbone. There has been a significant effort to understand structure …