Enzymatic catalysis has fueled considerable interest from chemists due to its high efficiency
and selectivity. However, the structural complexity and vulnerability hamper the application …

Benefitting from ultra‐high porosity, large specific surface area (SSA), and rich active sites,
metal–organic frameworks (MOFs) have emerged as a star material in energy and …

Abstract Electrochemical CO 2 reduction (CO 2 R) is an attractive option for storing
renewable electricity and for the sustainable production of valuable chemicals and fuels. In …

Gases like H2, N2, CO2, and CO are increasingly recognized as critical feedstock in “green”
energy conversion and as sources of nitrogen and carbon for the agricultural and chemical …

During the last decades, X-ray absorption spectroscopy (XAS) has become an
indispensable method for probing the structure and composition of heterogeneous catalysts …

Metalloenzymes catalyze a variety of reactions using a limited number of natural amino
acids and metallocofactors. Therefore, the environment beyond the primary coordination …

N2 is fixed as NH3 industrially by the Haber–Bosch process under harsh conditions,
whereas biological nitrogen fixation is achieved under ambient conditions, which has …

Ammonia (NH3) is industrially produced from dinitrogen (N2) and dihydrogen (H2) by the
Haber–Bosch process, although H2 is prepared from fossil fuels, and the reaction requires …

N-containing organic compounds are of vital importance to lives. Practical synthesis of
valuable N-containing organic compounds directly from dinitrogen (N2), not through …

Nitrogen fixation is essential for the maintenance of life and development of society,
however, the large bond dissociation energy and nonpolarity of the triple bond constitute a …