The Brookhart-type α-diimine nickel and palladium catalysts are one of the most examined
systems in the field of olefin polymerization. Even after more than twenty years of extensive …

Abstract α-Diimine Ni and Pd complexes are one of the most examined late-transition
organometallics in the application of catalyzed ethylene (co) polymerization. These …

Homogeneous nickel catalysts have a considerable track record for mediating ethylene
chain growth in the form of oligomerization and more recently polymerization. Within the …

The fascination of the well-defined metal catalysts for olefin polymerization is their capability
to control the properties of the polymer such as topology (linear to highly branched), range of …

The chemistry of redox-active bis (imino) acenaphthenes (BIAN, R-bian) and metal
complexes based on them has been a rapidly develo** field since the 1990s. The key …

Abstract Group 4 metal (Zr, Ti, Hf) catalysts for olefin polymerization and specifically those
based on non-metallocene complexes have continued to be a subject of intense study in …

A collection of ten related 1, 2-bis (imino) acenaphthene-nickel (II) halide complexes,[1-[2, 6-
{(C6H5) 2CH} 2-4-{C (CH3) 3}-C6H2N]-2-(ArN) C2C10H6] NiX2 (X= Br: Ar= 2, 6 …

Steric effects significantly impact catalytic performance of α-diimine nickel pre-catalyst
toward ethylene polymerization. In this contribution, a family of five new unsymmetrical 2, 3 …

For practicable elastomeric polyethylene, achieving high catalyst thermal stability and
activity, along with precise control of polymer properties such as branching density …

A new family of nickel halides (bromides Ni1–Ni5 and chlorides Ni6–Ni10) ligated by 1-(2, 6-
dibenzhydryl-4-nitrophenylimino)-2-(arylimino) acenaphthylene (Aryl= 2, 6-Me2C6H3L1, 2 …