Chemie frustrierter Lewis‐Paare: Entwicklung und Perspektiven

DW Stephan, G Erker - Angewandte Chemie, 2015 - Wiley Online Library
Abstract Der Begriff “frustrierte Lewis‐Paare”(FLPs) bezeichnet Kombinationen von Lewis‐
Säuren und Lewis‐Basen in Lösung, die aufgrund sterischer oder elektronischer Faktoren …

Frustrated Lewis pair chemistry: development and perspectives

DW Stephan, G Erker - Angewandte Chemie International …, 2015 - Wiley Online Library
Abstract Frustrated Lewis pairs (FLPs) are combinations of Lewis acids and Lewis bases in
solution that are deterred from strong adduct formation by steric and/or electronic factors …

B–N Lewis Pair Functionalization of Anthracene: Structural Dynamics, Optoelectronic Properties, and O2 Sensitization

K Liu, RA Lalancette, F Jäkle - Journal of the American Chemical …, 2017 - ACS Publications
The judicial placement of main group elements in conjugated structures is emerging as a
key route to novel functional hybrid materials. We demonstrate here that the formation of B …

Modular synthesis of organoboron helically chiral compounds: cutouts from extended helices

J Full, SP Panchal, J Götz, AM Krause… - Angewandte Chemie …, 2021 - Wiley Online Library
Two types of helically chiral compounds bearing one and two boron atoms were synthesized
by a modular approach. Formation of the helical scaffolds was executed by the introduction …

Direct and Base-Catalyzed Diboration of Alkynes Using the Unsymmetrical Diborane(4), pinB-BMes2

C Kojima, KH Lee, Z Lin… - Journal of the American …, 2016 - ACS Publications
In the absence of transition metal catalysts, the unsymmetrical diborane (4), pinB-BMes2,
reacted with alkynes to afford diborylalkenes. The isomer ratio of the products could be …

Low Band Gap Coplanar Conjugated Molecules Featuring Dynamic Intramolecular Lewis Acid–Base Coordination

C Zhu, ZH Guo, AU Mu, Y Liu… - The Journal of organic …, 2016 - ACS Publications
Ladder-type conjugated molecules with a low band gap and low LUMO level were
synthesized through an N-directed borylation reaction of pyrazine-derived donor–acceptor …

Modulare Synthese helikal‐chiraler Organobor‐Verbindungen: Ausschnitte verlängerter Helices

J Full, SP Panchal, J Götz, AM Krause… - Angewandte …, 2021 - Wiley Online Library
Abstract Zwei Arten helikal‐chiraler Verbindungen mit einem oder zwei Boratomen wurden
nach einem modularen Ansatz synthetisiert. Die Bildung der helikalen Strukturen erfolgte …

Electrochemical determination of indigo carmine in food and water samples using a novel platform based on chiral amine-bis (phenolate) boron complex

H Incebay, A Kilic - Dyes and Pigments, 2022 - Elsevier
For the electrochemical determination of indigo carmine (Ic), which is a common and toxic
dyestuff, a nanocomposite (LB/MWCNTs) was prepared with chiral amine-bis (phenolate) …

Exploiting the strong hydrogen bond donor properties of a borinic acid functionality for fluoride anion recognition

CH Chen, FP Gabbaï - Angewandte Chemie, 2018 - Wiley Online Library
Borinic acids have typically not been considered as hydrogen bond donor groups in
molecular recognition. Described herein is a bifunctional borane/borinic acid derivative (2) …

Unsolvated Al (C 6 F 5) 3: structural features and electronic interaction with ferrocene

J Chen, EYX Chen - Dalton Transactions, 2016 - pubs.rsc.org
Alkyl/aryl ligand exchange between AlEt3 and B (C6F5) 3 in hexanes enables the formation
and isolation of the unsolvated Al (C6F5) 3 as a crystalline solid, the structure of which has …